Pub. Date : 2009 Jun 15
PMID : 19456138
2 Functional Relationships(s)Download |
Sentence | Compound Name | Protein Name | Organism |
| 1 | We use density functional theory to investigate the mechanism of the catalytic dehydrogenation of AB by Ni N-heterocyclic carbene (NHC) complexes, which we show proceeds through Ni monocarbene and dicarbene species. | dicarbene | high mobility group nucleosomal binding domain 4 | Homo sapiens |
| 2 | Although Ni(NHC)(2) dehydrogenates AB, it competitively decomposes into a monocarbene species because AB readily displaces NHC from Ni(NHC)(2) and reaction of displaced NHC with abundant AB makes Ni monocarbene formation thermodynamically favored over the dicarbene catalyst. | dicarbene | high mobility group nucleosomal binding domain 4 | Homo sapiens |