Title : Rapid hydrolysis of model phosphate diesters by alkaline-earth cations in aqueous DMSO: speciation and kinetics.

Pub. Date : 2008 Dec 14

PMID : 19030623






1 Functional Relationships(s)
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1 Observed first-order rate constants in the presence of 1-2 mM Mg(II) or Ca(II) in neutral and weakly basic solutions were 10(8)-10(11) times higher than those for background hydrolysis at the same pH while in water additions of up to 50 mM metal produced <100-fold accelerations. Water carbonic anhydrase 2 Homo sapiens