Title : Chlorination increases the persistence of semiquinone free radicals derived from polychlorinated biphenyl hydroquinones and quinones.

Pub. Date : 2008 Nov 7

PMID : 18839991






1 Functional Relationships(s)
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1 Here we describe the synthesis of selected PCB metabolites with differing degrees of chlorination on the oxygenated phenyl ring, e.g., 4,4"-dichloro-biphenyl-2,5-diol, 3,6,4"-trichloro-biphenyl-2,5-diol, 3,4,6,-trichloro-biphenyl-2,5-diol, and their corresponding quinones. 3,6,4'-trichloro-biphenyl-2,5-diol pyruvate carboxylase Homo sapiens