Title : Enantioselective functionalisation of the C-2' position of 1,2,3,4,5-pentamethylazaferrocene via sparteine mediated lithiation: potential new ligands for asymmetric catalysis.

Pub. Date : 2008 Jan 21

PMID : 18175002






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 A novel C2-symmetric bis-pentamethylazaferrocene could be synthesised by an iron catalysed oxidative coupling of the enatioenriched C-2 lithio derivative and in the presence of a PhMe-Et2O solvent mixture proceeded in 97% ee. Toluene complement C2 Homo sapiens