Title : Enantioselective intramolecular aldol reaction mediated by a combination of L-amino Acid and Brønsted Acid to construct a bicyclic enedione containing a 7-membered ring.

Pub. Date : 2007 Dec

PMID : 18057744






1 Functional Relationships(s)
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1 The enantioselectivity of the intramolecular asymmetric aldol reaction of 1,3-cycloheptanedione bearing a C-2 methyl substituent, mediated by a series of combinations of L-amino acid and Bronsted acid, was examined in detail. Amino Acids complement C2 Homo sapiens