Title : A tandem aza-Claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides.

Pub. Date : 2007 Dec 6

PMID : 17990890






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1 The use of chiral Pd(II) catalysts such as (S)-COP-Cl during the rearrangement stage results in the preparation of these compounds in excellent yields and in high enantiomeric excess. Polydioxanone caspase recruitment domain family member 16 Homo sapiens