Title : Furanosteroid studies. Stereoselective synthesis of the A,B,E-ring core of wortmannin.

Pub. Date : 2007 Aug 16

PMID : 17655248






1 Functional Relationships(s)
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1 The TiCl4-catalyzed insertion of EtO2C-CH=O between C3 and C10 in furanoacid 14d is >98% stereoselective via a pathway involving chemoselective lactonization of equilibrating aldol intermediates 23alpha,beta (dynamic kinetic resolution). titanium tetrachloride homeobox C10 Homo sapiens