Title : A formal [3,3]-sigmatropic rearrangement route to quaternary alpha-vinyl amino acids: use of allylic N-PMP trifluoroacetimidates.

Pub. Date : 2006 Mar 2

PMID : 16494487






1 Functional Relationships(s)
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1 In the synthesis of the DOPA decarboxylase inactivator, alpha-vinyl-m-tyrosine, the new N-PMP trifluoroacetimidate rearranges much more efficiently than the corresponding trichloroacetimidate. trichloroacetamide dopa decarboxylase Homo sapiens