Title : Mild and selective palladium-catalyzed dimerization of terminal alkynes to form symmetrical (Z,Z)-1,4-dihalo-1,3-dienes.

Pub. Date : 2004 Nov 12

PMID : 15527303






1 Functional Relationships(s)
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1 In the presence of a catalytic amount of PdX(2) and 3 equiv of CuX(2) (X = Cl and Br), terminal alkynes were dimerized to afford (Z,Z)-1,4-dihalo-1,3-dienes in good yields. Bromine cut like homeobox 2 Homo sapiens