Title : The reaction of [FeII(tpa)] with H2O2 in acetonitrile and acetone--distinct intermediates and yet similar catalysis.

Pub. Date : 2004 Oct 11

PMID : 15372680






1 Functional Relationships(s)
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1 The reaction of [FeII(tpa)(OTf)2] (tpa=tris(2-pyridylmethyl)amine) and its related 5-Me3-tpa complex with hydrogen peroxide affords spectroscopically distinct iron(III)-peroxo intermediates in CH3CN and acetone. Acetone POU class 2 homeobox 2 Homo sapiens