Title : Olefins as steering ligands for homogeneously catalyzed hydrogenations.

Pub. Date : 2004 Sep 6

PMID : 15352102






1 Functional Relationships(s)
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1 Iridium(I) complexes containing a (5H-dibenzo[a,d]cyclohepten-5-yl)-phosphane (tropp(R); R = phosphorus-bound substituent = Ph, Cyc) as a rigid, concave-shaped, mixed phosphane olefin ligand were prepared and tested as catalyst precursors in the hydrogenation of imines. Iridium cytochrome c, somatic Homo sapiens