Title : An example of O2 binding in a cobalt(II) corrole system and high-valent cobalt-cyano and cobalt-alkynyl complexes.

Pub. Date : 2004 Mar 3

PMID : 14982461






4 Functional Relationships(s)
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Sentence
Compound Name
Protein Name
Organism
1 The reduced cobalt(II) complex, [(TBP)(8)CzCo(II)(py)](-), has been generated in situ and shown to bind dioxygen at low temperature to give [(TBP)(8)CzCo(III)(py)(O(2))](-). Oxygen TATA-box binding protein Homo sapiens
2 The reduced cobalt(II) complex, [(TBP)(8)CzCo(II)(py)](-), has been generated in situ and shown to bind dioxygen at low temperature to give [(TBP)(8)CzCo(III)(py)(O(2))](-). Oxygen TATA-box binding protein Homo sapiens
3 Exposure of [(TBP)(8)CzCo(II)(py)](-) to O(2) leads to the reversible formation of the cobalt(III)-superoxo complex [(TBP)(8)CzCo(III)(py)(O(2))](-), which has been characterized by EPR spectroscopy. Oxygen TATA-box binding protein Homo sapiens
4 Exposure of [(TBP)(8)CzCo(II)(py)](-) to O(2) leads to the reversible formation of the cobalt(III)-superoxo complex [(TBP)(8)CzCo(III)(py)(O(2))](-), which has been characterized by EPR spectroscopy. Oxygen TATA-box binding protein Homo sapiens