Title : Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols.

Pub. Date : 2003 Apr 3

PMID : 12659588






1 Functional Relationships(s)
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1 [reaction: see text] The geometrical isomers of 6-ethylidenedioxadisilacyclohexane were prepared by intramolecular hydrosilylation of an unsymmetrical disiloxane by the use of Pt (syn) and Ru (anti) catalysts. 6-ethylidenedioxadisilacyclohexane synemin Homo sapiens