Title : Dichloroacetylene is not the precursor to dichlorinated vinylcobaloxime and vinylcobalamin in cobalt catalyzed dechlorination of perchloro- and trichloroethylene.

Pub. Date : 2002 Nov 4

PMID : 12401092






3 Functional Relationships(s)
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Compound Name
Protein Name
Organism
1 This compound could be formed by nucleophilic vinylic substitution of cob(I)aloxime on TCE or its syn-addition to dichloroacetylene. dichloroacetylene metabolism of cobalamin associated B Homo sapiens
2 To evaluate the latter possibility, dichloroacetylene was reacted in this study with cob(I)aloxime. dichloroacetylene metabolism of cobalamin associated B Homo sapiens
3 Cob(I)alamin also reacts with chloroacetylene to provide cis-chlorovinylcobalamin in analogy to cob(I)aloxime, but it does not provide dichlorinated vinylcobalamins in the reaction with dichloroacetylene. dichloroacetylene metabolism of cobalamin associated B Homo sapiens