Title : Spin-state alteration from sterically enforced ligand rotation in bis(indenyl)chromium(II) complexes.

Pub. Date : 2002 Aug 14

PMID : 12167050






3 Functional Relationships(s)
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Protein Name
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1 The monosubstituted compounds (1-RC(9)H(6))(2)Cr (R = t-Bu, SiMe(3)) are prepared from the substituted lithium indenides and CrCl(2) in THF; they are high-spin species with four unpaired electrons. Chromium spindlin 1 Homo sapiens
2 Their spin state likely reflects that in the unknown monomeric (C(9)H(7))(2)Cr, which is calculated to have a high-spin (S = 2) ground state in the staggered configuration (180 degrees rotation angle). Chromium spindlin 1 Homo sapiens
3 Their spin state likely reflects that in the unknown monomeric (C(9)H(7))(2)Cr, which is calculated to have a high-spin (S = 2) ground state in the staggered configuration (180 degrees rotation angle). Chromium spindlin 1 Homo sapiens