Title : Boron-mediated aldol reaction of carboxylic esters: complementary anti- and syn-selective asymmetric aldol reactions.

Pub. Date : 2002 Jul 26

PMID : 12126413






1 Functional Relationships(s)
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1 Treatment of propionate esters with c-Hex2BOTf and triethylamine produces anti-aldol products, and that with Bu2BOTf and diisopropylethylamine gives syn-aldol products selectively after reaction with aldehydes. Dibutylboron trifluoromethanesulfonate synemin Homo sapiens