Title : Stoichiometry-controlled supramolecular chirality induction and inversion in bisporphyrin systems.

Pub. Date : 2002 Jan 24

PMID : 11796042






1 Functional Relationships(s)
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1 Chirality induction in the achiral syn ethane-bridged bis(zinc octaethylporphyrin) is achieved upon interaction with the enantiopure (R,R)-1,2-diphenylethylenediamine at the low molar excess region, to yield the right-handed chiral 1:1 tweezer complex. bis(zinc octaethylporphyrin) synemin Homo sapiens