Title : Regular and inverse secondary kinetic enthalpy effects (KHE) for the rate of inversion of thioether and 1,1'-biisoquinoline complexes of ruthenium and osmium.

Pub. Date : 2001 Dec 17

PMID : 11735474






1 Functional Relationships(s)
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1 Since third-row transition metal complexes tend to have larger bond dissociation enthalpies (BDE) than their second-row congeners, we conclude the difference in reactivities of 3(M=Ru)(+) versus 3(M=Os)(+) and 4(M=Ru)(+) versus 4(M=Os)(+) are attributed to electronic effects. Metals homeobox D13 Homo sapiens