Title : Total synthesis of (+/-)-scopadulin.

Pub. Date : 2001 Jul 13

PMID : 11442413






1 Functional Relationships(s)
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1 Stereoselective construction of a quaternary carbon at C-4 was achieved by alpha-alkylation of the cyano group and conversion of the sterically hindered cyano group to a methyl group via our novel reaction for conversion of primary aliphatic amines into alcohols. Carbon complement C4A (Rodgers blood group) Homo sapiens