Title : Carbenerhodium complexes of the half-sandwich-type: synthesis, substitution, and addition reactions.

Pub. Date : 2000 Dec 15

PMID : 11192078






1 Functional Relationships(s)
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1 While the reaction of 2a, c with C2H4 yields [(eta5-C5H5)Rh(C2H4)(L)] (14, 15) and the trisubstituted olefin Ph2C=CHCH3 (16), treatment of 2a, c with RN3 leads to the cleavage of both the Rh-EiPr3 and Rh=CPh2 bonds and gives the chelate complexes [(eta5-C5H5)Rh(kappa2-RNNNNR)] (19, 20). ethylene drosha ribonuclease III Homo sapiens