Title : Stereoselective reaction of alpha-sulfinyl carbanion derived from chiral 2-(Trialkylsilyl)ethyl sulfoxides: evidence for a novel silicon-oxygen interaction

Pub. Date : 2000 Jan 28

PMID : 10813959






1 Functional Relationships(s)
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1 Interaction between the silicon in the trialkylsilyl group and the carbonyl oxygen in nucleophiles was postulated to stabilize the transition state, leading preferably to the syn diastereisomers. Oxygen synemin Homo sapiens