Title : Energetics of the proposed rate-determining step of the glyoxalase I reaction.

Pub. Date : 1999 Jun 18

PMID : 10403382






1 Functional Relationships(s)
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1 The proposed rate-limiting step of the reaction catalyzed by glyoxalase I is the proton abstraction from the C1 carbon atom of the substrate by a glutamate residue, resulting in a high-energy enolate intermediate. Carbon glyoxalase I Homo sapiens