PMID-sentid Pub_year Sent_text compound_name comp_offset prot_official_name organism prot_offset 29083160-2 2017 PDAs 1 and 2a-c are themselves easily accessed through photochemically initiated topochemical polymerization of diynes 3 and 4a-c in the crystal. Diynes 112-118 PDA1 Homo sapiens 0-15 30344447-1 2018 The robust CoI precatalyst [CpCo(P{OEt}3)(trans-MeO2CHC=CHCO2Me)] was investigated in cyclotrimerizations, furnishing benzenes and pyridines from triynes, diynes and nitriles, comparing the influence of different ways of energy supply; namely, irradiation and conventional (thermal) or microwave heating. Diynes 155-161 mitochondrially encoded cytochrome c oxidase I Homo sapiens 11-14 29676817-2 2018 Diyne cross-metathesis (DYCM) studies with 13 C-labeled diyne PhC 13 C-13 C CPh (3*) revealed that this reaction proceeds through reversible carbon-carbon triple-bond cleavage and formation according to the conventional mechanism of alkyne metathesis. Diynes 0-5 carboxypeptidase E Homo sapiens 76-79 29676817-2 2018 Diyne cross-metathesis (DYCM) studies with 13 C-labeled diyne PhC 13 C-13 C CPh (3*) revealed that this reaction proceeds through reversible carbon-carbon triple-bond cleavage and formation according to the conventional mechanism of alkyne metathesis. Diynes 56-61 carboxypeptidase E Homo sapiens 76-79 29652161-2 2018 The synthetic approach features an SN2"- syn displacement of carbamates by cuprates to set the challenging quaternary stereogenic center at C17 and a Pd-catalyzed construction of the triene system in the presence of a diyne moiety. Diynes 218-223 synemin Homo sapiens 4-7 29171703-0 2018 Homo- and Copolycyclotrimerization of Aromatic Internal Diynes Catalyzed with Co2 (CO)8 : A Facile Route to Microporous Photoluminescent Polyphenylenes with Hyperbranched or Crosslinked Architecture. Diynes 56-62 complement C2 Homo sapiens 78-81 29171703-1 2018 This study reports the first Co2 (CO)8 -catalyzed [2+2+2] polycyclotrimerization by the transformation of internal ethynyl groups of aromatic diyne monomers. Diynes 142-147 complement C2 Homo sapiens 29-32 32321241-3 2020 Herein, we design a molecule with cumulene moiety (Br2C=C=C=CBr2) and employ STM tip manipulation to achieve the molecular skeleton rearrangement from cumulene to diyne moiety (Br-C C-C C-Br). Diynes 163-168 sulfotransferase family 1A member 3 Homo sapiens 77-80 26613420-5 2015 The X-ray crystal structure of 5b in complex with VDR reveals that the ligand binds similarly to the natural hormone, but the diyne moiety is slightly bent (angles around the diyne 5 to 8 ) with respect to the original diyne vitamin D compound 6 in VDR (<1 ) due to steric hindrance with helix 12. Diynes 126-131 vitamin D receptor Homo sapiens 50-53 26613420-5 2015 The X-ray crystal structure of 5b in complex with VDR reveals that the ligand binds similarly to the natural hormone, but the diyne moiety is slightly bent (angles around the diyne 5 to 8 ) with respect to the original diyne vitamin D compound 6 in VDR (<1 ) due to steric hindrance with helix 12. Diynes 175-180 vitamin D receptor Homo sapiens 50-53 15252576-3 2004 It was found that the diyne ligand easily reacts with all these complexes to give [HOs(3)(CO)8(PR3)-[mu3, eta1:eta3:eta1)-(CH(3)-C-C=CH-CH=C-O)]] complexes (V, VI and VII, respectively) containing the "Os3C3" pentagonal pyramid cluster framework. Diynes 22-27 proteinase 3 Homo sapiens 95-98 15252576-3 2004 It was found that the diyne ligand easily reacts with all these complexes to give [HOs(3)(CO)8(PR3)-[mu3, eta1:eta3:eta1)-(CH(3)-C-C=CH-CH=C-O)]] complexes (V, VI and VII, respectively) containing the "Os3C3" pentagonal pyramid cluster framework. Diynes 22-27 secreted phosphoprotein 1 Homo sapiens 106-110 15252576-3 2004 It was found that the diyne ligand easily reacts with all these complexes to give [HOs(3)(CO)8(PR3)-[mu3, eta1:eta3:eta1)-(CH(3)-C-C=CH-CH=C-O)]] complexes (V, VI and VII, respectively) containing the "Os3C3" pentagonal pyramid cluster framework. Diynes 22-27 secreted phosphoprotein 1 Homo sapiens 116-120 34469135-0 2021 Enantioselective Rh(II)-Catalyzed Desymmetric Cycloisomerization of Diynes: Constructing Furan-Fused Dihydropiperidines with an Alkyne-Substituted Aza-Quaternary Stereocenter. Diynes 68-74 Rh blood group D antigen Homo sapiens 17-23 34469135-1 2021 Described herein is an enantioselective dirhodium(II)-catalyzed cycloisomerization of diynes achieved by the strategy of desymmetrization, which not only represents a new cycloisomerization reaction of diynes but also constitutes the first Rh(II)-catalyzed asymmetric intramolecular cycloisomerization of 1,6-diynes. Diynes 86-92 Rh blood group D antigen Homo sapiens 240-246 34469135-1 2021 Described herein is an enantioselective dirhodium(II)-catalyzed cycloisomerization of diynes achieved by the strategy of desymmetrization, which not only represents a new cycloisomerization reaction of diynes but also constitutes the first Rh(II)-catalyzed asymmetric intramolecular cycloisomerization of 1,6-diynes. Diynes 202-208 Rh blood group D antigen Homo sapiens 240-246 27703122-2 2016 The sp-C-H...N hydrogen-bonding interaction is strong enough to promote the deliberate cocrystallization of a series of diynes with a series of dipyridines. Diynes 120-126 surfactant protein C Homo sapiens 4-8 24280731-3 2014 In this review, achievements in this field are presented in three major parts (the syn-syn, anti-anti, and syn-anti addition reactions of diynes or two alkyne molecules). Diynes 138-144 synemin Homo sapiens 83-86 24280731-3 2014 In this review, achievements in this field are presented in three major parts (the syn-syn, anti-anti, and syn-anti addition reactions of diynes or two alkyne molecules). Diynes 138-144 synemin Homo sapiens 87-90 24280731-3 2014 In this review, achievements in this field are presented in three major parts (the syn-syn, anti-anti, and syn-anti addition reactions of diynes or two alkyne molecules). Diynes 138-144 synemin Homo sapiens 87-90 22812460-0 2012 Synthesis of Enantiopure tertiary skipped diynes via one-pot desymmetrizing TMS-cleavage. Diynes 42-48 PYD and CARD domain containing Homo sapiens 76-79 22812460-1 2012 Enantiopure tetrasubstituted skipped diynes were readily synthesized from N-protected amino esters upon addition of lithium TMS-acetylide which was found to be desymmetrizing through one-pot selective TMS-cleavage. Diynes 37-43 PYD and CARD domain containing Homo sapiens 124-127 22812460-1 2012 Enantiopure tetrasubstituted skipped diynes were readily synthesized from N-protected amino esters upon addition of lithium TMS-acetylide which was found to be desymmetrizing through one-pot selective TMS-cleavage. Diynes 37-43 PYD and CARD domain containing Homo sapiens 201-204 20827441-1 2008 The utility of Sato"s titanium-mediated reduction of alkynes towards the synthesis of all cis-poly(phenylenevinylene)s (PPVs) is demonstrated by the syn-selective reduction of a variety of model diynes as well as a tetrayne. Diynes 195-201 synemin Homo sapiens 73-76 18273857-3 2008 The diyne crystallized in the chiral monoclinic space group P2(1) from toluene/hexane. Diynes 4-9 cyclin dependent kinase inhibitor 1A Homo sapiens 60-65 11829598-2 2002 Conjugated diynes undergo dimerization in the presence of acetic acid and catalytic amounts of Pd(PPh3)4. Diynes 11-17 caveolin 1 Homo sapiens 98-102 11028006-0 2000 Cyclization of Terminal Diynes Catalyzed by Thiolate-Bridged Diruthenium Complexes: A Simple Synthetic Route to endo-Macrocyclic (Z)-1-En-3-ynes This work was supported by a Grant-in-Aid for Specially Promoted Research (09102004) from the Ministry of Education, Science, Sports, and Culture, Japan. Diynes 24-30 activation induced cytidine deaminase Homo sapiens 183-186 31347203-4 2019 Another route involves Rosenthal"s reagent (Cp2 Zr(py)Me3 SiC CSiMe3 ), which then reacts with a diyne or monoyne moiety. Diynes 97-102 ceruloplasmin Homo sapiens 44-47 31589434-1 2019 The bench-stable cationic bis(sigma-B-H) aminoborane complex [Fe(PNPNMe-iPr)(H)(eta2-H2B=NMe2)]+ (2) efficiently catalyzes the semi-hydrogenation of internal alkynes, 1,3-diynes and 1,3-enynes. Diynes 167-177 DNA polymerase iota Homo sapiens 80-84