PMID-sentid	Pub_year	Sent_text	compound_name	comp_offset	prot_official_name	organism	prot_offset
33428402-8	2021	These allowed for the observation of sequential displacement of the metal-bound solvent by the alkyne, C-C bond formation though insertion in the Mn-C bond, and a slower protonation step by HOAc to generate the product of a Mn(I)-catalyzed C-H bond functionalization reaction.	mn(i)	224-229	hypoacusis 2 (autosomal recessive)	Homo sapiens	190-194
29738258-9	2018	Importantly, (kappa4-Ph2PPrPDI)Mn(mu-eta1,eta2-CO)K(18-crown-6) was found to react instantaneously with either HBF4 OEt2 or HOTf to evolve H2 and generate the corresponding Mn(I) complex, [(Ph2PPrPDI)Mn(CO)][BF4] or [(Ph2PPrPDI)Mn(CO)][OTf], respectively.	mn(i)	173-178	secreted phosphoprotein 1	Homo sapiens	37-41
31141384-1	2019	A series of Mn(I) catalysts containing imidazole-based chiral PNN tridentate ligands with controllable "side arm" groups have been established, enabling the asymmetrical hydrogenation of unsymmetrical benzophenones with outstanding activity (up to 13 000 TON) and excellent enantioselectivity (up to >99% ee).	mn(i)	12-17	pinin, desmosome associated protein	Homo sapiens	62-65
30986073-1	2019	A highly active Mn(I) catalyst based on a nonsymmetric PN3-ligand scaffold for the N-alkylation of amines with alcohols utilizing the borrowing hydrogen methodology is reported.	mn(i)	16-21	sodium voltage-gated channel alpha subunit 10	Homo sapiens	55-58
29738258-9	2018	Importantly, (kappa4-Ph2PPrPDI)Mn(mu-eta1,eta2-CO)K(18-crown-6) was found to react instantaneously with either HBF4 OEt2 or HOTf to evolve H2 and generate the corresponding Mn(I) complex, [(Ph2PPrPDI)Mn(CO)][BF4] or [(Ph2PPrPDI)Mn(CO)][OTf], respectively.	mn(i)	173-178	DNA polymerase iota	Homo sapiens	42-46
11669694-6	1997	The results indicated that the distinct electronic effects between methaneselenolate and benzeneselenolate play a key role in stabilizing the neutral Mn(I)-Co(III)-Mn(I)-selenolate complexes.	mn(i)	150-155	mitochondrially encoded cytochrome c oxidase III	Homo sapiens	159-162
11669694-6	1997	The results indicated that the distinct electronic effects between methaneselenolate and benzeneselenolate play a key role in stabilizing the neutral Mn(I)-Co(III)-Mn(I)-selenolate complexes.	mn(i)	164-169	mitochondrially encoded cytochrome c oxidase III	Homo sapiens	159-162