PMID-sentid Pub_year Sent_text compound_name comp_offset prot_official_name organism prot_offset 34870288-2 2021 As the HMDS-substituted one underwent methyl migration from silicon to boron transforming the putative borinium ion to a silylium ion, (Mes-B-TMP)+ can initiate cyanosilylation and catalyse hydrosilylation of ketones and aldehydes. silylium 121-129 epithelial membrane protein 1 Homo sapiens 142-145 33215771-0 2021 Activation of CS2 and CO2 by Silylium Cations. silylium 29-37 chorionic somatomammotropin hormone 2 Homo sapiens 14-17 29116666-0 2017 C-F Bond Activation by Silylium Cation/Phosphine Frustrated Lewis Pairs: Mono-Hydrodefluorination of PhCF3 , PhCF2 H and Ph2 CF2. silylium 23-31 ATPase H+ transporting accessory protein 1 Homo sapiens 111-114 28731275-0 2017 Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-a-vis Silylene and Silylium Ion. silylium 96-104 BORA aurora kinase A activator Homo sapiens 50-54 17388597-5 2007 Hence, formation of Re(O)Cl2(H)(PPh3)2 (4a) proceeds via a sigma-adduct followed by heterolytic cleavage of the Si-H bond and transfer of silylium (Et3Si+) to chloride. silylium 138-146 caveolin 1 Homo sapiens 32-36 33031611-0 2021 Reversible silylium transfer between P-H and Si-H donors. silylium 11-19 phenylalanine hydroxylase Homo sapiens 37-40 27860103-2 2016 These results not only explain the stereoselectivity of these silylium-ion-ACDC reactions but should also guide the development of more effective ion-pairing asymmetric organocatalysts. silylium 62-70 adiponectin, C1Q and collagen domain containing Homo sapiens 75-79 24435914-1 2014 Upon reaction of gaseous Me3SiF with the in situ prepared Lewis acid Al(OR(F))3, the stable ion-like silylium compound Me3 Si-F-Al(OR(F))3 1 forms. silylium 101-109 ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens 69-79 24435914-1 2014 Upon reaction of gaseous Me3SiF with the in situ prepared Lewis acid Al(OR(F))3, the stable ion-like silylium compound Me3 Si-F-Al(OR(F))3 1 forms. silylium 101-109 ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens 128-138 24435914-3 2014 Thus, in reactions of 1 with soft nucleophiles (Nu), such as phosphanes, the silylium side interacts in an orbital-controlled manner, with formation of [Me3Si-Nu](+) and the weakly coordinating [F-Al(OR(F))3](-) or [((F)RO)3Al-F-Al(OR(F))3](-) anions. silylium 77-85 ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens 197-207 24435914-3 2014 Thus, in reactions of 1 with soft nucleophiles (Nu), such as phosphanes, the silylium side interacts in an orbital-controlled manner, with formation of [Me3Si-Nu](+) and the weakly coordinating [F-Al(OR(F))3](-) or [((F)RO)3Al-F-Al(OR(F))3](-) anions. silylium 77-85 ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens 229-239