PMID-sentid	Pub_year	Sent_text	compound_name	comp_offset	prot_official_name	organism	prot_offset
21748537-5	2012	RESULTS: UV-exposure of solid human insulin results in photodissociation of the C-terminal intrachain disulfide bond, leading to formation of a CysS( ) thiyl radical pair which ultimately disproportionates into thiol and thioaldehyde species.	thiyl	152-157	insulin	Homo sapiens	36-43
23354473-6	2013	The reactivity of peptide thiyl, perthiyl, and sulfinyl radical ions was evaluated based on ion/molecule reactions toward organic disulfides, allyl iodide, organic thiol, and oxygen, which followed in order of thiyl (RS ) > perthiyl (RSS ) > sulfinyl (RSO ).	thiyl	26-31	Russell-Silver dwarfism	Homo sapiens	237-240
12377051-7	2002	Analysis of the electron-transfer rate constant in terms of Marcus theory yields an effective self-exchange rate constant for the thiolate/thiyl redox couple that is in reasonable agreement with the value derived previously from the reaction of TGA with [IrCl(6)](2-).	thiyl	139-144	T-box transcription factor 1	Homo sapiens	245-248
21666221-7	2011	Mutagenesis of this key cysteine to alanine abolished eNOS thiyl radical formation and uncoupled eNOS, leading to increased superoxide generation.	thiyl	59-64	nitric oxide synthase 3	Homo sapiens	54-58