PMID-sentid	Pub_year	Sent_text	compound_name	comp_offset	prot_official_name	organism	prot_offset
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	hydrosilane	56-67	secreted phosphoprotein 1	Homo sapiens	170-174
31189060-7	2019	For the C C double bond hydrosilylation, except for the mCH pathway whose rate-determining step is the hydrosilane addition reaction, the rate-determining steps of the CH, aCH, and DH pathways are Si-C reductive elimination reactions.	hydrosilane	103-114	modifier of chinchilla	Mus musculus	56-59
31189060-7	2019	For the C C double bond hydrosilylation, except for the mCH pathway whose rate-determining step is the hydrosilane addition reaction, the rate-determining steps of the CH, aCH, and DH pathways are Si-C reductive elimination reactions.	hydrosilane	103-114	modifier of chinchilla	Mus musculus	57-59
30259918-1	2018	The present study discloses the synthesis of aryl/vinyl carboxylic acids from Csp2-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate.	hydrosilane	170-181	regulator of calcineurin 2	Homo sapiens	78-82
28922608-5	2017	Hence, in nonclassical hydrosilane complexes such as Cp2Ti(PMe3)(HSiMe3-nCln) (with n = 1-3) the sign of J(Si,H) changes from minus to plus with increasing number of chloro substituents n and maps the rising degree of oxidative addition.	hydrosilane	23-34	nicalin	Homo sapiens	72-76
31184780-5	2019	Then, Int2 reacts with hydrosilane to form hydrosilane sigma-complex Int3; this is named path 1A.	hydrosilane	23-34	fibroblast growth factor 3	Homo sapiens	6-10
31184780-5	2019	Then, Int2 reacts with hydrosilane to form hydrosilane sigma-complex Int3; this is named path 1A.	hydrosilane	23-34	notch receptor 4	Homo sapiens	69-73
31184780-5	2019	Then, Int2 reacts with hydrosilane to form hydrosilane sigma-complex Int3; this is named path 1A.	hydrosilane	43-54	fibroblast growth factor 3	Homo sapiens	6-10
31184780-5	2019	Then, Int2 reacts with hydrosilane to form hydrosilane sigma-complex Int3; this is named path 1A.	hydrosilane	43-54	notch receptor 4	Homo sapiens	69-73
31184780-10	2019	In path 2, 1 reacts with hydrosilane to form Int5, which then forms adduct Int6 with substrate through Si-N interaction between substrate and PhSiH3 .	hydrosilane	25-36	integrator complex subunit 5	Homo sapiens	45-49
31184780-10	2019	In path 2, 1 reacts with hydrosilane to form Int5, which then forms adduct Int6 with substrate through Si-N interaction between substrate and PhSiH3 .	hydrosilane	25-36	eukaryotic translation initiation factor 3 subunit E	Homo sapiens	75-79
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	hydrosilane	56-67	DNA polymerase iota	Homo sapiens	187-191
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	hydrosilane	133-144	secreted phosphoprotein 1	Homo sapiens	170-174
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	hydrosilane	133-144	DNA polymerase iota	Homo sapiens	187-191
21743899-2	2011	According to the calculations, the reaction proceeds via five steps: (1) oxidative addition of hydrosilane, (2) hydride migration to carbon-carbon double bond of tert-butyl acrylate, which determines the chirality at C2, (3) tautomerization from rhodium bound C-enolate to rhodium bound O-enolate, (4) intramolecular aldol reaction, which determines the chirality at C3 and consequently the anti/syn-selectivity, and (5) reductive elimination to release aldol product.	hydrosilane	95-106	synemin	Homo sapiens	396-399