PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 10815973-0 2000 On-line time-resolved laser-induced fluorescence of UO2(NO3)2.2TBP in supercritical fluid CO2 Time-resolved laser-induced fluorescence has been shown to be effective for on-line measurement of uranyl chelates in supercritical carbon dioxide. uranyl 193-199 TATA-box binding protein Homo sapiens 63-66 16833878-5 2005 In MD simulations, which started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl by TBP is observed and the yield increases with the TBP concentration. uranyl 88-94 TATA-box binding protein Homo sapiens 130-133 16833878-5 2005 In MD simulations, which started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl by TBP is observed and the yield increases with the TBP concentration. uranyl 88-94 TATA-box binding protein Homo sapiens 130-133 16851014-0 2005 Uranyl extraction by beta-diketonate ligands to SC-CO2: theoretical studies on the effect of ligand fluorination and on the synergistic effect of TBP. uranyl 0-6 TATA-box binding protein Homo sapiens 146-149 16851014-1 2005 We report theoretical investigations on the effect of H --> F substitution in acetylacetonate ligands in order to understand why fluorination promotes the extraction of uranyl to supercritical CO(2) with a marked synergistic effect of tri-n-butyl phosphate "TBP". uranyl 172-178 TATA-box binding protein Homo sapiens 261-264 26149535-8 2015 This explains why noninteger values are often derived by analysis of DU versus [TBP] plots to determine the number of TBP molecules involved in the extraction of uranyl in an ionic-liquid phase. uranyl 162-168 TATA-box binding protein Homo sapiens 80-83 26149535-8 2015 This explains why noninteger values are often derived by analysis of DU versus [TBP] plots to determine the number of TBP molecules involved in the extraction of uranyl in an ionic-liquid phase. uranyl 162-168 TATA-box binding protein Homo sapiens 118-121 24601645-4 2014 Describing uranyl and nitrate ions with integer charges (+2 and -1, respectively) is shown to exaggerate the hydrophilicity and surface activity of the UO2(NO3)2(TBP)2 complex. uranyl 11-17 TATA-box binding protein Homo sapiens 162-165 24815040-4 2014 These calculations suggest that the differential hardness of the two extractants is responsible for the preferential binding/complexation of TBP to uranyl, whereas the softer DHOA and the bulky nature of the extractant lead to stronger binding/complexation of DHOA to Pu(IV). uranyl 148-154 TATA-box binding protein Homo sapiens 141-144 24601645-0 2014 Liquid-liquid extraction of uranyl by TBP: the TBP and ions models and related interfacial features revisited by MD and PMF simulations. uranyl 28-34 TATA-box binding protein Homo sapiens 38-41 24601645-0 2014 Liquid-liquid extraction of uranyl by TBP: the TBP and ions models and related interfacial features revisited by MD and PMF simulations. uranyl 28-34 TATA-box binding protein Homo sapiens 47-50 23746355-9 2013 These features suggest that uranyl complexation by amide ligands occurs "right at the interface", displaying marked analogies with the liquid-liquid extraction of uranyl by TBP (tri-n-butyl phosphate). uranyl 28-34 TATA-box binding protein Homo sapiens 173-176 23746355-9 2013 These features suggest that uranyl complexation by amide ligands occurs "right at the interface", displaying marked analogies with the liquid-liquid extraction of uranyl by TBP (tri-n-butyl phosphate). uranyl 163-169 TATA-box binding protein Homo sapiens 173-176 21887434-6 2011 The uranyl complexes were found to be UO(2)(2+) (TBP)(3) for the cationic exchange mechanism, UO(2)(NO(3))(2)(TBP)(2) for the neutral mechanism and UO(2)(NO(3))(3)(-) (TBP) for the anionic exchange mechanism. uranyl 4-10 TATA-box binding protein Homo sapiens 49-52 21887434-6 2011 The uranyl complexes were found to be UO(2)(2+) (TBP)(3) for the cationic exchange mechanism, UO(2)(NO(3))(2)(TBP)(2) for the neutral mechanism and UO(2)(NO(3))(3)(-) (TBP) for the anionic exchange mechanism. uranyl 4-10 TATA-box binding protein Homo sapiens 110-113 21887434-6 2011 The uranyl complexes were found to be UO(2)(2+) (TBP)(3) for the cationic exchange mechanism, UO(2)(NO(3))(2)(TBP)(2) for the neutral mechanism and UO(2)(NO(3))(3)(-) (TBP) for the anionic exchange mechanism. uranyl 4-10 TATA-box binding protein Homo sapiens 110-113 20967313-4 2010 Moreover, our simulation results suggest that the experimentally observed complex UO(2)(NO(3))(2) 2TBP is formed after the migration of the aforementioned complexes into the organic phase by means of a reorganization of the nitrate binding mode from mono to bidentate which removes the excess oxygen atoms bound to uranyl. uranyl 315-321 TATA-box binding protein Homo sapiens 99-102 21445434-3 2011 Raman spectroscopic studies show the dissolved uranyl ions are coordinated with TBP in the IL phase with a molar ratio of (UO(2))(2+) : TBP = 1 : 2. uranyl 47-53 TATA-box binding protein Homo sapiens 80-83 21445434-3 2011 Raman spectroscopic studies show the dissolved uranyl ions are coordinated with TBP in the IL phase with a molar ratio of (UO(2))(2+) : TBP = 1 : 2. uranyl 47-53 TATA-box binding protein Homo sapiens 136-139 21445434-6 2011 Absorption spectra of the extracted uranyl species in the sc-CO(2) phase suggests the presence of a UO(2)(TBP)(2)(NO(3))(2) and HNO(3) adduct probably of the form UO(2)(TBP)(2)(NO(3))(2) HNO(3). uranyl 36-42 TATA-box binding protein Homo sapiens 106-109 21445434-6 2011 Absorption spectra of the extracted uranyl species in the sc-CO(2) phase suggests the presence of a UO(2)(TBP)(2)(NO(3))(2) and HNO(3) adduct probably of the form UO(2)(TBP)(2)(NO(3))(2) HNO(3). uranyl 36-42 TATA-box binding protein Homo sapiens 169-172 19283821-1 2009 Uranyl ions [UO(2)](2+) in aqueous nitric acid can be extracted into supercritical CO(2) (sc-CO(2)) by using an imidazolium-based ionic liquid with tri-n-butyl phosphate (TBP) as a complexing agent. uranyl 0-6 TATA-box binding protein Homo sapiens 171-174 19283821-3 2009 The form of the uranyl complex extracted into the sc-CO(2) phase was identified to be [UO(2)(NO(3))(2)(TBP)(2)]. uranyl 16-22 TATA-box binding protein Homo sapiens 103-106