PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 19117492-2 2009 A series of single photon emission computed tomography imaging agents (SPECT) utilizing the organometallic radioactive imaging species, fac-99mTc(OH(2))(3)(CO)(3)+, were prepared on the basis of the structure of Flutamide, a potent nonsteroidal antiandrogen prostate cancer drug. Water 146-151 FA complementation group C Homo sapiens 136-139 17140248-1 2006 The water exchange process on fac-[(CO)3Mn(H2O)3]+ and fac-[(CO)3Tc(H2O)3]+ was kinetically investigated by 17O NMR as a function of the acidity, temperature, and pressure. Water 43-46 FA complementation group C Homo sapiens 30-33 19035614-2 2009 We developed convenient reactions for the synthesis of small, water stable fac-[TcO(3)(tacn-R)](+) complexes ((99)Tc and (99m)Tc, tacn = 1,4,7-triazacyclononane, R = H, -CH(2)-C(6)H(5), -CH(2)-C(6)H(4)COOH). Water 62-67 FA complementation group C Homo sapiens 75-78 17914811-6 2007 31Palpha-31Palpha EXSY cross-peaks indicate that the fac-[Re(CO)3(H2O)({Palpha,Pbeta}MDP)]- isomers interchange slowly on the NMR time scale, with an average k approximately equal to 0.8 s(-1) at 32 degrees C; the EXSY cross-peaks could arise from chirality changes at only Re(I) or at only Palpha. Water 66-69 FA complementation group C Homo sapiens 53-56 17914811-7 2007 Guanosine 5"-diphosphate (5"-GDP), with a ribose moiety and a Re(I)-binding base, formed both possible diastereomers (RRe and SRe) of the fac-[Re(CO)3(H2O)({N7,Pbeta}GDP)]- macrochelate, with one slightly more abundant diastereomer suggested to be RRe by Mn2+ ion 1H NMR signal line-broadening combined with distances from molecular models. Water 151-154 FA complementation group C Homo sapiens 138-141 17914811-10 2007 The similarity of the rate constants for interchange of fac-[Re(CO)3(H2O)({Palpha,Pbeta}MDP)]- and fac-[Re(CO)3(H2O)({N7,Pbeta}GDP)]- adducts suggest strongly that interchange of Pbeta and H2O coordination positions accounts for the EXSY cross-peaks present in the spectra of all adducts. Water 69-72 FA complementation group C Homo sapiens 56-59 17914811-10 2007 The similarity of the rate constants for interchange of fac-[Re(CO)3(H2O)({Palpha,Pbeta}MDP)]- and fac-[Re(CO)3(H2O)({N7,Pbeta}GDP)]- adducts suggest strongly that interchange of Pbeta and H2O coordination positions accounts for the EXSY cross-peaks present in the spectra of all adducts. Water 112-115 FA complementation group C Homo sapiens 99-102 17914811-10 2007 The similarity of the rate constants for interchange of fac-[Re(CO)3(H2O)({Palpha,Pbeta}MDP)]- and fac-[Re(CO)3(H2O)({N7,Pbeta}GDP)]- adducts suggest strongly that interchange of Pbeta and H2O coordination positions accounts for the EXSY cross-peaks present in the spectra of all adducts. Water 112-115 FA complementation group C Homo sapiens 99-102 19035614-0 2009 Syntheses of high-valent fac-[99mTcO3]+ complexes and [3+2] cycloadditions with alkenes in water as a direct labelling strategy. Water 91-96 FA complementation group C Homo sapiens 25-28 18298058-1 2008 Reaction of [NEt4]2[ReBr3(CO)3] with 2,4-pentanedione (acac) yields a complex of the type fac-Re(acac)(OH2)(CO)3 (1) under aqueous conditions. Water 103-107 FA complementation group C Homo sapiens 90-93 17443264-1 2007 The intercalation of fac-tricarbonylchloro-1,10-phenanthrolinerhenium(i) (Re(phen)(CO)(3)Cl) within zirconium phosphate (ZrP) has been achieved using a hydrated ZrP phase that possesses six water molecules per formula unit. Water 190-195 FA complementation group C Homo sapiens 21-24 17140248-0 2006 Relevance of the ligand exchange rate and mechanism of fac-[(CO)3M(H2O)3]+ (M = Mn, Tc, Re) complexes for new radiopharmaceuticals. Water 67-70 FA complementation group C Homo sapiens 55-58 17140248-1 2006 The water exchange process on fac-[(CO)3Mn(H2O)3]+ and fac-[(CO)3Tc(H2O)3]+ was kinetically investigated by 17O NMR as a function of the acidity, temperature, and pressure. Water 4-9 FA complementation group C Homo sapiens 30-33 17140248-1 2006 The water exchange process on fac-[(CO)3Mn(H2O)3]+ and fac-[(CO)3Tc(H2O)3]+ was kinetically investigated by 17O NMR as a function of the acidity, temperature, and pressure. Water 4-9 FA complementation group C Homo sapiens 55-58 17140248-1 2006 The water exchange process on fac-[(CO)3Mn(H2O)3]+ and fac-[(CO)3Tc(H2O)3]+ was kinetically investigated by 17O NMR as a function of the acidity, temperature, and pressure. Water 68-71 FA complementation group C Homo sapiens 55-58 17140248-2 2006 Up to pH 6.3 and 4.4, respectively, the exchange rate is not affected by the acidity, thus demonstrating that the contribution of the monohydroxo species fac-[(CO)3M(OH)(H2O)2] is not significant, which correlates well with a higher pKa for these complexes compared to the homologue fac-[(CO)3Re(H2O)3]+ complex. Water 170-173 FA complementation group C Homo sapiens 154-157 17140248-6 2006 The substitution of water in fac-[(CO)3M(H2O)3]+ by dimethyl sulfide (DMS) is slightly faster than that by CH3CN: 3 times faster for Mn, 1.5 times faster for Tc, and 1.2 times faster for Re. Water 20-25 FA complementation group C Homo sapiens 29-32 16854039-2 2006 The fully optimized complexes of fac-[Tc(OH(2))(CO(3))](+) and mer-[Tc(OH(2))(CO(3))](+) show geometries that compare favorably with the X-ray data. Water 41-47 FA complementation group C Homo sapiens 33-36 16854039-2 2006 The fully optimized complexes of fac-[Tc(OH(2))(CO(3))](+) and mer-[Tc(OH(2))(CO(3))](+) show geometries that compare favorably with the X-ray data. Water 71-77 FA complementation group C Homo sapiens 33-36 16311642-2 2005 Thus, the thermodynamic product of the reaction between cis,fac-[RuCl(2)(dmso-S)(3)(dmso-O)]() and cbdc in a number of different reaction conditions is the dinuclear species with two bridging cbdc units fac-[Ru(micro-cbdc-O,O")(dmso-S)(3)(H(2)O)](2) (2). Water 239-244 FA complementation group C Homo sapiens 60-63 16311642-2 2005 Thus, the thermodynamic product of the reaction between cis,fac-[RuCl(2)(dmso-S)(3)(dmso-O)]() and cbdc in a number of different reaction conditions is the dinuclear species with two bridging cbdc units fac-[Ru(micro-cbdc-O,O")(dmso-S)(3)(H(2)O)](2) (2). Water 239-244 FA complementation group C Homo sapiens 203-206 15046515-0 2004 The organometallic fac-[(CO)3Mn(H2O)3]+ aquaion: base-hydrolysis and kinetics of H2O-substitution. Water 32-35 FA complementation group C Homo sapiens 19-22 15046515-0 2004 The organometallic fac-[(CO)3Mn(H2O)3]+ aquaion: base-hydrolysis and kinetics of H2O-substitution. Water 81-84 FA complementation group C Homo sapiens 19-22 12517123-0 2003 Aerobic oxidation of methyl p-tolyl sulfide catalyzed by a remarkably labile heteroscorpionate RuII-aqua complex, fac-[RuII(H2O)(dpp)(tppm)]2+. Water 124-127 FA complementation group C Homo sapiens 114-117 34788019-3 2021 Reaction of either PyAH or the pharmacophore-bearing PyAH ligand (L1H) with fac-(M(CO)3)+ core in water yielded the intermediate fac-(M(CO)3(PyA)(H2O)) complexes. Water 98-103 FA complementation group C Homo sapiens 76-79 12425618-0 2002 Ferromagnetic coupling between low- and high-spin iron(III) ions in the tetranuclear complex fac-[[FeIII[HB(pz)3](CN)2(mu-CN)]3FeIII(H2O)3]* 6H2O ([HB(pz)3]- = hydrotris(1-pyrazolyl)borate). Water 133-136 FA complementation group C Homo sapiens 93-96 34788019-3 2021 Reaction of either PyAH or the pharmacophore-bearing PyAH ligand (L1H) with fac-(M(CO)3)+ core in water yielded the intermediate fac-(M(CO)3(PyA)(H2O)) complexes. Water 98-103 FA complementation group C Homo sapiens 129-132 34788019-3 2021 Reaction of either PyAH or the pharmacophore-bearing PyAH ligand (L1H) with fac-(M(CO)3)+ core in water yielded the intermediate fac-(M(CO)3(PyA)(H2O)) complexes. Water 146-149 FA complementation group C Homo sapiens 76-79 34788019-3 2021 Reaction of either PyAH or the pharmacophore-bearing PyAH ligand (L1H) with fac-(M(CO)3)+ core in water yielded the intermediate fac-(M(CO)3(PyA)(H2O)) complexes. Water 146-149 FA complementation group C Homo sapiens 129-132 35414170-13 2022 The purpose of this Account is to provide an overview of the breadth of new research perspectives that emerged from the development of water-soluble fac-(Ir(ppy))3 complexes (ppy = 2-phenylpyridine) with sulfonated ligands. Water 135-140 FA complementation group C Homo sapiens 149-152 33949526-3 2021 The Re-thiosulfate complex in 2 was characterized in two solvated crystal structures {Na(fac-[Re(CO)3(bpy)(S2O3)]) 1.75H2O C2H5OH}4 (2 + 0.75H2O + C2H5OH)4 and (fac-[Re(CO)3(bpy)(H2O)]) (fac-[Re(CO)3(bpy)(S2O3)]) 4H2O (3). Water 119-122 FA complementation group C Homo sapiens 89-92 33949526-2 2021 Here, we compare the cytotoxicity and cellular uptake of two Re(i) compounds fac-[(Re(CO)3(bpy)(H2O)](CF3SO3) (1) and Na(fac-[(Re(CO)3(bpy)(S2O3)]) H2O (bpy = 2,2"-bipyridine) (2). Water 96-99 FA complementation group C Homo sapiens 77-80 31490511-5 2019 Each of the three technetium-99m labelled naphthalimide complexes were successfully produced from fac-[99mTc(CO)3(H2O)3]+ in 15 minutes at 70 C and isolated in radiochemical yields ranging from 60-95% with radiochemical purities greater than 95%. Water 114-117 FA complementation group C Homo sapiens 98-101 34007509-2 2021 Since FAC has abundant surface functional groups and a desired porous structure that is favorable for the removal of As(V) in contaminated water, FAC has greatly enhanced the As(V) adsorption capacity of the original BC. Water 139-144 FA complementation group C Homo sapiens 6-9 34007509-2 2021 Since FAC has abundant surface functional groups and a desired porous structure that is favorable for the removal of As(V) in contaminated water, FAC has greatly enhanced the As(V) adsorption capacity of the original BC. Water 139-144 FA complementation group C Homo sapiens 146-149 31740907-1 2020 Rhenium(i) di- and tri-carbonyl complexes of the form fac-[Re(CO)3(L,L"-Bid)X] and [Re(CO)2(L,L"-Bid)X2], where X = aqua (H2O), methanol (CH3OH), triphenylphosphine (PPh3), 1,3,5-triaza-7-phosphaadamantane (PTA), tricyclohexylphosphine (PCy3) and L,L"-Bid = O,O" bidentate ligands (tropolone = TropH and 3-hydroxyflavone = FlavH) and N,O bidentate ligands (8-hydroxyquinoline = QuinH, 5,7-chloro-8-hydroxyquinoline = diCl-QuinH and quinoline-2,4-dicarboxylic acid = QuinH2), were synthesized and unambiguously characterized by 1H-, 13C-and 31P-NMR, IR, UV/Vis and micro-analysis. Water 122-125 FA complementation group C Homo sapiens 54-57 30925213-3 2019 In this combined experimental and computational study, we show that imidazolium functionalization of molecular fac-Mn(CO)3 bipyridine complexes results in CO2 reduction at mild electrochemical potentials in the presence of H2O. Water 223-226 FA complementation group C Homo sapiens 111-114 29949364-3 2018 In the first, the intermediate fac-[Re(CO)3(quin)(H2O)] aqua complex 2 is generated from the fac-[NEt4]2[Re(CO)3Br3] precursor, together with the brominated products fac-[Re(CO)3(quinH)(Br)] 1a and fac-[NEt4][Re(CO)3(quin)(Br)] 1b, in low yield. Water 50-53 FA complementation group C Homo sapiens 31-34 30070288-1 2018 It is known that both cis,fac-[RuCl2(DMSO)3(H2O)] (1a) and trans,cis,cis-[RuCl2(DMSO)2(H2O)2] (2a) complexes, which are formed on the dissolution of trans and cis-isomers of [RuCl2(DMSO)4] in water, demonstrate light-induced anticancer activity. Water 44-47 FA complementation group C Homo sapiens 26-29 30566121-0 2019 Electrochemical CO2 reduction in water at carbon cloth electrodes functionalized with a fac-Mn(apbpy)(CO)3Br complex. Water 33-38 FA complementation group C Homo sapiens 88-91 29778927-6 2018 The corresponding 99mTc complexes were synthesized from fac-[99mTc(CO)3(H2O)3]+, purified by HPLC, and obtained with average 41-76% decay-corrected radiochemical yields and with >99% radiochemical purity. Water 72-75 FA complementation group C Homo sapiens 56-59 29949364-3 2018 In the first, the intermediate fac-[Re(CO)3(quin)(H2O)] aqua complex 2 is generated from the fac-[NEt4]2[Re(CO)3Br3] precursor, together with the brominated products fac-[Re(CO)3(quinH)(Br)] 1a and fac-[NEt4][Re(CO)3(quin)(Br)] 1b, in low yield. Water 50-53 FA complementation group C Homo sapiens 93-96 29949364-3 2018 In the first, the intermediate fac-[Re(CO)3(quin)(H2O)] aqua complex 2 is generated from the fac-[NEt4]2[Re(CO)3Br3] precursor, together with the brominated products fac-[Re(CO)3(quinH)(Br)] 1a and fac-[NEt4][Re(CO)3(quin)(Br)] 1b, in low yield. Water 50-53 FA complementation group C Homo sapiens 93-96 29949364-3 2018 In the first, the intermediate fac-[Re(CO)3(quin)(H2O)] aqua complex 2 is generated from the fac-[NEt4]2[Re(CO)3Br3] precursor, together with the brominated products fac-[Re(CO)3(quinH)(Br)] 1a and fac-[NEt4][Re(CO)3(quin)(Br)] 1b, in low yield. Water 50-53 FA complementation group C Homo sapiens 93-96 26090963-0 2015 Characterization of Water Coordination to Ferrous Nitrosyl Complexes with fac-N2O, cis-N2O2, and N2O3 Donor Ligands. Water 20-25 FA complementation group C Homo sapiens 74-77 29376536-1 2018 Treatment of Lambda-fac-[Co(d-pen-N,S)3]3- (d-H2pen = d-penicillamine) with Cu+ in water gave a stable CoCu complex, LambdaLambda-[Co2Cu3(d-pen)6]3- ([1]3-), having three thiolato-copper(i)-thiolato moieties that bridge two cobalt(iii) centres. Water 83-88 FA complementation group C Homo sapiens 20-23 28512575-1 2017 Multiple possibilities for the coordination of fac-[Re(CO)3(H2O)3]+ to a protein have been determined and include binding to Asp, Glu, Arg and His amino-acid residues as well as to the C-terminal carboxylate in the vicinity of Leu and Pro. Water 60-63 FA complementation group C Homo sapiens 47-50 28106930-1 2017 The electrochemical behavior of fac-[Mn(pdbpy)(CO)3 Br] (pdbpy=4-phenyl-6-(phenyl-2,6-diol)-2,2"-bipyridine) (1) in acetonitrile under Ar, and its catalytic performances for CO2 reduction with added water, 2,2,2-trifluoroethanol (TFE), and phenol are discussed in detail. Water 199-204 FA complementation group C Homo sapiens 32-35 28470321-1 2017 A Mn(i) tris(2-pyridylmethyl)amine complex fac-[Mn(kappa3-tpa) (CO)3]+OTf- carries out electrocatalytic hydrogen evolution from neutral water in acetonitrile. Water 136-141 FA complementation group C Homo sapiens 43-46 26090963-2 2015 These complexes formed a comparative family, {FeNO}(7)(N2Ox)(H2O)3-x with x = 1-3, where the labile coordination sites for the binding of NO and solvent water were fac for x = 1 and cis for x = 2. Water 153-158 FA complementation group C Homo sapiens 164-167 25878826-1 2015 The crystal structures of two solvates of fac-tri-chlorido-tris-(tri-methyl-phosphane-kappaP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3] H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3] 0.5CH3OH. Water 134-139 FA complementation group C Homo sapiens 42-45 24574031-1 2014 The reaction of fac-[M(III)F3(Me3tacn)] x H2O with Gd(NO3)3 5H2O affords a series of fluoride-bridged, trigonal bipyramidal {Gd(III)3M(III)2} (M = Cr (1), Fe (2), Ga (3)) complexes without signs of concomitant GdF3 formation, thereby demonstrating the applicability even of labile fluoride-complexes as precursors for 3d-4f systems. Water 42-45 FA complementation group C Homo sapiens 16-19 24199833-2 2013 The complexes were synthesized through the corresponding fac-[M(CO)3(H2O)(OO)] (M = Re, (99m)Tc) intermediate aqua complex. Water 69-72 FA complementation group C Homo sapiens 57-60 24199833-3 2013 In the presence of phosphine, replacement of the H2O molecule of the intermediate complex at room temperature generates the neutral tricarbonyl monophosphine fac-[Re(CO)3(P)(OO)] complex, while under reflux conditions further replacement of the trans to the phosphine carbonyl generates the new stable dicarbonyl bisphosphine complex cis-trans-[Re(CO)2(P)2(OO)]. Water 49-52 FA complementation group C Homo sapiens 158-161 23088314-1 2012 Water-soluble fac-[Re(CO)(3)(L,L"-Bid)(X)] (L,L"-Bid = tropolonato, X = H(2)O, methanol) complexes have been synthesized, and the aqua and methanol substitution reactions were investigated in water (pH range 6.3-10.0) and methanol, respectively, and compared. Water 0-5 FA complementation group C Homo sapiens 14-17 23088314-1 2012 Water-soluble fac-[Re(CO)(3)(L,L"-Bid)(X)] (L,L"-Bid = tropolonato, X = H(2)O, methanol) complexes have been synthesized, and the aqua and methanol substitution reactions were investigated in water (pH range 6.3-10.0) and methanol, respectively, and compared. Water 192-197 FA complementation group C Homo sapiens 14-17 22054130-0 2011 Water-stable fac-{TcO3}+ complexes - a new field of technetium chemistry. Water 0-5 FA complementation group C Homo sapiens 13-16 22054130-7 2011 In analogy to [OsO(4)] and [RuO(4)], complexes containing the fac-{TcO(3)}(+) core undergo with alkenes metal-mediated, vicinal cis-dihydroxylation reactions (alkene-glycol interconversion) in water via a (3+2)-cycloaddition reaction. Water 194-199 FA complementation group C Homo sapiens 62-65 22054130-8 2011 Therefore, water-stable fac-{(99m)TcO(3)}(+) complexes pave the way for a new labeling strategy for radiopharmaceutical applications, based on (3+2)-cycloaddition reactions. Water 11-16 FA complementation group C Homo sapiens 24-27 23939285-0 2013 Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl. Water 27-32 FA complementation group C Homo sapiens 132-135 22441138-1 2012 Magnetite-filled micelles capture fac-[M(OH(2))(3)(CO)(3)](+) complexes (M = (99m)Tc, Re), creating versatile self-assembled constructs for multimodal SPECT/MR/optical imaging and radiopharmaceutical guided delivery. Water 41-47 FA complementation group C Homo sapiens 34-37 22008632-2 2012 1,2,3-Triazole analogs were synthesized by click chemistry and labeled with fac-[ReCO3(H2O)3]Br and fac-[188ReCO3(H2O)3]+. Water 86-91 FA complementation group C Homo sapiens 76-79