PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
16526813-0	2006	Efficient copper-free PdCl2(PCy3)2-catalyzed Sonogashira coupling of aryl chlorides with terminal alkynes.	aryl chlorides	69-83	phosducin like 2	Homo sapiens	22-27	
25333944-2	2014	Deactivated aryl bromides and activated aryl chlorides were cross-coupled with 5-formyl-2-furanylboronic in the presence of (Bu)4N(+)OAc(-) using the bis-triphenylphosphine CatCart  PdCl2(PPh3)2-DVB.	aryl chlorides	40-54	phosducin like 2	Homo sapiens	182-187	
23952320-3	2013	The coupling reactions with aryl chlorides progressed in the presence of PdCl2dcpp (3 mol %) and CuI/MeNHCH2CH2OH (20 mol %) in anhydrous DMF without bases.	aryl chlorides	28-42	phosducin like 2	Homo sapiens	73-78	
16526813-1	2006	Under copper-free conditions and with Cs2CO3 as a base, PdCl2(PCy3)2 showed high catalytic activity for cross-coupling of electron-rich, electron-neutral, and electron-deficient aryl chlorides with a variety of terminal alkynes in DMSO at 100-120 degrees C affording internal arylated alkynes in good to excellent yields.	aryl chlorides	178-192	phosducin like 2	Homo sapiens	56-61