PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 10866624-4 2000 Studies on a series of mono, di-, and trisubstituted cyclopentenes are reported in which trans-vicinal-additions favor a syn-selective approach of electrophiles to the cyclopentene system. Cyclopentanes 53-65 synemin Homo sapiens 121-124 22364202-3 2012 The selectivity is induced in the cyclization step, and while the enantioselectivity results from the syn/anti orientation around the C-N enamine bond, the diastereoselectivity mainly results from the syn/anti configuration of the substituents in the forming cyclopentane ring. Cyclopentanes 259-271 synemin Homo sapiens 102-105 22364202-3 2012 The selectivity is induced in the cyclization step, and while the enantioselectivity results from the syn/anti orientation around the C-N enamine bond, the diastereoselectivity mainly results from the syn/anti configuration of the substituents in the forming cyclopentane ring. Cyclopentanes 259-271 synemin Homo sapiens 201-204 12974653-1 2003 Allenes with a nucleophilic functionality connected to the alpha-carbon atom have been shown to be versatile building blocks for the syn-thesis of gamma-butenolides, gamma-lactams, gamma-iminolactones, vinylic epoxides, 4-amino-2-alkenols, 2-amino-3-alkenols, 2,5-dihydrofurans, furans, vinylic cyclopropanes, and cyclopentenes, depending on the nature of the nucleophilic centers. Cyclopentanes 314-327 synemin Homo sapiens 133-136 11674564-4 1999 All the cycloadditions occurred exclusively on the pi-face syn to the etheno bridge of 2, thereby in cases of the cycloadditions with anthracene, cyclopentadiene, 1,3-cyclohexadiene, and 6,6-dimethylfulvene producing the corresponding adducts 11a, 18b, 22b, and 23b that contain three double bonds aligned in parallel. Cyclopentanes 146-161 synemin Homo sapiens 59-62 11674049-2 1998 The ranges of activation energies for syn addition are large relative to those for anti addition, which are all similar to the activation energy for cyclopentadiene itself. Cyclopentanes 149-164 synemin Homo sapiens 38-41 11674049-4 1998 Deformation of the 5-fluoro-, 5-hydroxy-, and 5-amino-1,3-cyclopentadienes into their syn transition state geometries is predicted to require less energy than deformation of cyclopentadiene itself, which is in accord with experimental observation of syn addition with these dienes. Cyclopentanes 58-73 synemin Homo sapiens 86-89 11674049-4 1998 Deformation of the 5-fluoro-, 5-hydroxy-, and 5-amino-1,3-cyclopentadienes into their syn transition state geometries is predicted to require less energy than deformation of cyclopentadiene itself, which is in accord with experimental observation of syn addition with these dienes. Cyclopentanes 58-73 synemin Homo sapiens 250-253 30873839-1 2019 We describe a stereoselective method for obtaining multigram quantities of molecular basket 1 syn in overall 11% yield, using inexpensive cyclopentadiene and diethyl fumarate as starting materials. Cyclopentanes 138-153 synemin Homo sapiens 94-97