PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 33881099-7 2021 Upon activation with Al2Et3Cl3 in toluene, these complexes showed high activities in isoprene polymerization affording cis-1,4 enriched polymers with a moderate molecular weight (0.85-4.72 x 104 Da). Toluene 34-41 suppressor of cytokine signaling 1 Homo sapiens 119-124 32914974-2 2020 cis-1,2-dihydrocatechols 5 (X= Me and Cl), which are available in homochiral form through the whole-cell biotransformation of toluene and chlorobenzene, respectively, undergo Diels-Alder cycloaddition reactions with certain electron-deficient dienophiles at 19 kbar (1.9 GPa). Toluene 126-133 suppressor of cytokine signaling 1 Homo sapiens 0-5 30965837-3 2017 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). Toluene 226-233 suppressor of cytokine signaling 1 Homo sapiens 154-159 30965837-3 2017 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). Toluene 226-233 suppressor of cytokine signaling 1 Homo sapiens 248-253 11749603-2 2001 cis-1-Silylmethyl-2-vinylcyclopropanes 17 and 19 undergo facile 1,5-hydrogen transposition upon mild thermolysis in benzene or toluene solution (80-110 degrees C) to give nearly quantitative yields of ring-opened 1-silyl-1,4-diene products. Toluene 127-134 suppressor of cytokine signaling 1 Homo sapiens 0-5