PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 24605985-2 2014 Thus, the mechanisms of both the oxidative C-H bond cleavage of toluene derivatives and sulfoxidation of thioanisole derivatives by [(N4Py)Fe(IV)(O)](2+) in the presence of HOTf and Sc(OTf)3 have been unified as the rate-determining electron transfer, which is coupled with binding of [(N4Py)Fe(IV)(O)](2+) by proton (PCET) and Sc(OTf)3 (MCET). Toluene 64-71 POU class 5 homeobox 1 Homo sapiens 182-190 24605985-2 2014 Thus, the mechanisms of both the oxidative C-H bond cleavage of toluene derivatives and sulfoxidation of thioanisole derivatives by [(N4Py)Fe(IV)(O)](2+) in the presence of HOTf and Sc(OTf)3 have been unified as the rate-determining electron transfer, which is coupled with binding of [(N4Py)Fe(IV)(O)](2+) by proton (PCET) and Sc(OTf)3 (MCET). Toluene 64-71 POU class 5 homeobox 1 Homo sapiens 328-336 18670121-2 2008 By using Yb(OTf)3 as a catalyst, each calix[4 and 6]arenes was afforded, in an overall yield of 20.7% and 11.8% in the "3+1" and "5+1" approaches, respectively, and 24.6% and 19.9% using a "1+1" approach with chlorobenzene and toluene as refluxing solvents, respectively. Toluene 227-234 POU class 5 homeobox 1 Homo sapiens 12-17 12381174-1 2002 The addition of pinacol allylboronic esters to aromatic and aliphatic aldehydes smoothly occurred at -78 degrees C in toluene in the presence of a catalytic amount of AlCl3 or Sc(OTf)3 (10 mol %) to give the corresponding homoallyl alcohols in high yields. Toluene 118-125 POU class 5 homeobox 1 Homo sapiens 176-184