PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
12381174-1	2002	The addition of pinacol allylboronic esters to aromatic and aliphatic aldehydes smoothly occurred at -78 degrees C in toluene in the presence of a catalytic amount of AlCl3 or Sc(OTf)3 (10 mol %) to give the corresponding homoallyl alcohols in high yields.	Toluene	118-125	POU class 5 homeobox 1	Homo sapiens	176-184	
18670121-2	2008	By using Yb(OTf)3 as a catalyst, each calix[4 and 6]arenes was afforded, in an overall yield of 20.7% and 11.8% in the "3+1" and "5+1" approaches, respectively, and 24.6% and 19.9% using a "1+1" approach with chlorobenzene and toluene as refluxing solvents, respectively.	Toluene	227-234	POU class 5 homeobox 1	Homo sapiens	12-17	
24605985-2	2014	Thus, the mechanisms of both the oxidative C-H bond cleavage of toluene derivatives and sulfoxidation of thioanisole derivatives by [(N4Py)Fe(IV)(O)](2+) in the presence of HOTf and Sc(OTf)3 have been unified as the rate-determining electron transfer, which is coupled with binding of [(N4Py)Fe(IV)(O)](2+) by proton (PCET) and Sc(OTf)3 (MCET).	Toluene	64-71	POU class 5 homeobox 1	Homo sapiens	182-190	
24605985-2	2014	Thus, the mechanisms of both the oxidative C-H bond cleavage of toluene derivatives and sulfoxidation of thioanisole derivatives by [(N4Py)Fe(IV)(O)](2+) in the presence of HOTf and Sc(OTf)3 have been unified as the rate-determining electron transfer, which is coupled with binding of [(N4Py)Fe(IV)(O)](2+) by proton (PCET) and Sc(OTf)3 (MCET).	Toluene	64-71	POU class 5 homeobox 1	Homo sapiens	328-336