PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 32022364-4 2020 Coordination of Co(II) ions into the porphyrin subunit followed by addition of appropriate monodentate nitrogen-based additives to function as axial ligands enable the radical carbene transfer reactions to styrene derivatives to occur exclusively through the cavity of the macrocycle to afford cyclopropane-linked rotaxanes in excellent 95% yield. cyclopropane 294-306 mitochondrially encoded cytochrome c oxidase II Homo sapiens 16-22 20735129-3 2010 The Co(II)-based catalytic system can be operated in a one-time protocol under mild conditions, affording the desired cyclopropane products in high yields with both high diastereo- and enantioselectivity. cyclopropane 118-139 mitochondrially encoded cytochrome c oxidase II Homo sapiens 4-9 34260202-4 2021 Through the fine-tuning of D2-symmetric chiral amidoporphyrins as the supporting ligands, the Co(II)-catalyzed radical cascade process, which proceeds in a single operation under mild conditions, enables asymmetric construction of multisubstituted cyclopropane-fused tetrahydrofurans bearing three contiguous stereogenic centers, including two all-carbon quaternary centers, in high yields with excellent stereoselectivities. cyclopropane 248-260 mitochondrially encoded cytochrome c oxidase II Homo sapiens 94-100