PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 34374276-5 2021 In the two-step reaction (route III), an endocyclic Cd2+ complex, (Cd(L)I2) (3), obtained in the first step was utilized in the following reaction with Cu(CH3CN)4PF6, giving rise to an endo/exocyclic tetranuclear Cu+ complex, (Cu4(L)2(CH3CN)6)(PF6)4 (4), via Cd2+ 2Cu+ substitution, which is not accessible by conventional procedures. Copper 213-216 CD2 molecule Homo sapiens 52-55 34403904-2 2022 This study demonstrates the electrochemically assisted uptake and release of cadmium ions (Cd2+) using a redox-active Cu-based metal-organic framework (MOF) electrode. Copper 118-120 CD2 molecule Homo sapiens 91-94 34403904-4 2022 This work utilized copper within the CuGA structure as a redox center to attract Cd2+ by means of Cu2+/Cu+ reduction, exhibiting rapid uptake kinetics and a much higher capacity (>60 mg g-1) compared to the case without electrochemical assistance (~15 mg g-1). Copper 19-25 CD2 molecule Homo sapiens 81-84 34403904-4 2022 This work utilized copper within the CuGA structure as a redox center to attract Cd2+ by means of Cu2+/Cu+ reduction, exhibiting rapid uptake kinetics and a much higher capacity (>60 mg g-1) compared to the case without electrochemical assistance (~15 mg g-1). Copper 103-106 CD2 molecule Homo sapiens 81-84 34403904-5 2022 In addition, by applying an opposite overpotential to induce the re-oxidation of copper, the facile recovery of Cd2+ and the regeneration of the electrode were possible without regenerants. Copper 81-87 CD2 molecule Homo sapiens 112-115 34403904-7 2022 This work presents the feasibility of a Cu-based MOF electrode as a reusable platform for the efficient removal of Cd2+, supporting the continued discovery and development of new Faradaic electrodes for electrochemical wastewater treatments. Copper 40-42 CD2 molecule Homo sapiens 115-118 34311356-6 2021 DW and FT aging both increased the adsorption capacity of Cu2+, but decreased that of Cd2+ in the three biochars, resulting in a reduction in Cu bioavailability and increase in Cd bioavailability in the biochars after the saturated adsorption of Cu2+ and Cd2+. Copper 142-144 CD2 molecule Homo sapiens 86-89 34374276-5 2021 In the two-step reaction (route III), an endocyclic Cd2+ complex, (Cd(L)I2) (3), obtained in the first step was utilized in the following reaction with Cu(CH3CN)4PF6, giving rise to an endo/exocyclic tetranuclear Cu+ complex, (Cu4(L)2(CH3CN)6)(PF6)4 (4), via Cd2+ 2Cu+ substitution, which is not accessible by conventional procedures. Copper 213-216 CD2 molecule Homo sapiens 259-262 34374276-6 2021 Solution studies by comparative NMR and electrospray ionization mass spectroscopy also support metal substitution by showing the stronger binding affinity of Cu+ over Cd2+. Copper 158-161 CD2 molecule Homo sapiens 167-170 26617434-8 2015 Once inside the covellite particles, Cd2+ and Hg2+ cations engaged in exchange reactions, pushing the expelled Cu+ ions toward the not-yet exchanged regions in the same particles, or out to the solution, from where they could be recaptured by other covellite nanoparticles/domains. Copper 111-114 CD2 molecule Homo sapiens 37-40 2959502-7 1987 For the 3-metal cluster, the affinity is found to decrease in the order Cu+ greater than Cd2+ greater than Zn2+ with Cd2+ greater than Zn2+ for the 4 metal cluster and Cd2+ (4-metal cluster) greater than Cd2+ (3-metal cluster). Copper 72-75 CD2 molecule Homo sapiens 89-92 2959502-7 1987 For the 3-metal cluster, the affinity is found to decrease in the order Cu+ greater than Cd2+ greater than Zn2+ with Cd2+ greater than Zn2+ for the 4 metal cluster and Cd2+ (4-metal cluster) greater than Cd2+ (3-metal cluster). Copper 72-75 CD2 molecule Homo sapiens 117-120 2959502-7 1987 For the 3-metal cluster, the affinity is found to decrease in the order Cu+ greater than Cd2+ greater than Zn2+ with Cd2+ greater than Zn2+ for the 4 metal cluster and Cd2+ (4-metal cluster) greater than Cd2+ (3-metal cluster). Copper 72-75 CD2 molecule Homo sapiens 117-120 2959502-7 1987 For the 3-metal cluster, the affinity is found to decrease in the order Cu+ greater than Cd2+ greater than Zn2+ with Cd2+ greater than Zn2+ for the 4 metal cluster and Cd2+ (4-metal cluster) greater than Cd2+ (3-metal cluster). Copper 72-75 CD2 molecule Homo sapiens 117-120 6825199-3 1983 During this period, renal copper content doubles due to the replacement of thionein-bound Cd2+ with Cu2+. Copper 26-32 CD2 molecule Homo sapiens 90-93 31717598-4 2019 Nano-copper was deposited onto the surface of carbon fiber to enhance the current concentration and mass transfer rate of Cd2+ during measurement, which improved the electrochemical detection sensitivity significantly (by up to 3.7 x 108 nA/nM) and broadened the linear range to 10~105 nM. Copper 5-11 CD2 molecule Homo sapiens 122-125 34449598-3 2021 In Cd2+ and Cu2+ ion sorption tests, the synthesized dihydrazide-based PAMH hydrogel particles exhibited sorption capacities of 85 mg/g for copper and 47 mg/g for cadmium. Copper 140-146 CD2 molecule Homo sapiens 3-6 35624611-8 2022 The use of this enzymic membrane proved to be advantageous when reversible inhibitors such as the copper ion (Cu2+) were present in water samples, as Cu2+ can interfere with Cd2+ and cause erroneous results. Copper 98-104 CD2 molecule Homo sapiens 174-177 35065379-0 2022 Functionalized Cu-based metal oxide nanoparticles with enhanced Cd+2 adsorption capacity and their ecotoxicity assessment by molecular docking. Copper 15-17 CD2 molecule Homo sapiens 64-68 35224594-4 2022 In the case of djurleite Cu1.94S NDs, the Cu+ was immediately substituted by Cd2+ and solid wurtzite CdS NDs were produced. Copper 42-45 CD2 molecule Homo sapiens 77-80 33294387-3 2020 We hypothesized that Cd2+ could be transported into cells via a membrane copper (Cu) transporter, CTR1. Copper 73-79 CD2 molecule Homo sapiens 21-24 33294387-3 2020 We hypothesized that Cd2+ could be transported into cells via a membrane copper (Cu) transporter, CTR1. Copper 81-83 CD2 molecule Homo sapiens 21-24 30602243-6 2019 The selectivity study in bimetal aqueous systems using copper, lead and zinc metals showed the adsorption order of Cu2+ > Cd2+ > Zn2+ > Pb2+. Copper 55-61 CD2 molecule Homo sapiens 125-128 17102865-5 2006 However, the Cd2+ complex with [17](DBF)N2O2 exhibits the highest value of stability constant for the whole series of metal ions studied, indicating that this ligand reveals a remarkable selectivity for cadmium(II) in the presence of all the metal ions studied, except copper(II), indicating that this ligand reveals a remarkable selectivity for cadmium(II) in the presence of the mentioned metal ions. Copper 269-275 CD2 molecule Homo sapiens 13-16