PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 24004243-1 2013 The four-coordinate scandium phosphinidene complex, [LSc(mu-PAr)]2 (L = (MeC(NDIPP)CHC(Me)(NCH2CH2N((i)Pr)2)), DIPP = 2,6-((i)Pr)2C6H3; Ar = 2,6-Me2C6H3) (1), has been synthesized in good yield, and its reactivity has been investigated. Phosphinidene 29-42 jumping translocation breakpoint Homo sapiens 60-63 24004243-3 2013 First, two-electron reduction occurs when substrates as 2,2"-bipyridine, elemental selenium, elemental tellurium, Me3P S, or Ph3P E (E = S, Se) is used, resulting in the oxidative coupling of two phosphinidene ligands 2[PAr](2-) into a diphosphene ligand [ArP-PAr](2-). Phosphinidene 196-209 jumping translocation breakpoint Homo sapiens 220-223 24004243-3 2013 First, two-electron reduction occurs when substrates as 2,2"-bipyridine, elemental selenium, elemental tellurium, Me3P S, or Ph3P E (E = S, Se) is used, resulting in the oxidative coupling of two phosphinidene ligands 2[PAr](2-) into a diphosphene ligand [ArP-PAr](2-). Phosphinidene 196-209 jumping translocation breakpoint Homo sapiens 260-263 15316986-0 2004 Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study. Phosphinidene 52-65 jumping translocation breakpoint Homo sapiens 81-84 15316986-4 2004 Transient 16-electron phosphinidene complex [Cp*Ir=PAr] could not be detected experimentally. Phosphinidene 22-35 jumping translocation breakpoint Homo sapiens 51-54