PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 25384112-0 2014 Highly efficient activation of organosilanes with eta2-aldehyde nickel complexes: key for catalytic syntheses of aryl-, vinyl-, and alkynyl-benzoxasiloles. Nickel 64-70 DNA polymerase iota Homo sapiens 50-54 21449600-0 2011 Theoretical insights into the nature of nickel-carbon dioxide interactions in Ni(PH3)2(eta2-CO2). Nickel 40-46 DNA polymerase iota Homo sapiens 87-91 33107502-1 2020 [LSi(eta2-P4)] (L = CH[C(Me)N(Dipp)][C(CH2)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. Nickel 156-162 DNA polymerase iota Homo sapiens 5-9 18729364-0 2008 Eta2-organoazide complexes of nickel and their conversion to terminal imido complexes via dinitrogen extrusion. Nickel 30-36 DNA polymerase iota Homo sapiens 0-4 18594727-0 2008 Polycarbide nickel clusters containing interstitial Ni(eta2-C2)4 and Ni2(micro-eta2-C2)4 acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C2)4(CO)32]3- and [Ni22(C2)4(CO)28Cl]3-. Nickel 12-18 DNA polymerase iota Homo sapiens 55-59 18594727-0 2008 Polycarbide nickel clusters containing interstitial Ni(eta2-C2)4 and Ni2(micro-eta2-C2)4 acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C2)4(CO)32]3- and [Ni22(C2)4(CO)28Cl]3-. Nickel 12-18 DNA polymerase iota Homo sapiens 79-83 16159269-0 2005 AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Nickel 71-77 DNA polymerase iota Homo sapiens 40-44 16159269-0 2005 AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Nickel 71-77 DNA polymerase iota Homo sapiens 56-60 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 78-84 DNA polymerase iota Homo sapiens 47-51 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 78-84 DNA polymerase iota Homo sapiens 63-67 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 110-116 DNA polymerase iota Homo sapiens 47-51 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 110-116 DNA polymerase iota Homo sapiens 63-67 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 110-116 DNA polymerase iota Homo sapiens 47-51 16159269-2 2005 AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. Nickel 110-116 DNA polymerase iota Homo sapiens 63-67 15225021-1 2004 The reaction of (2-SiH3C6H4)2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2 afforded a new silylnickel complex, which, in the solid state, was determined to be a bis(silyl)eta2-(Si-H)nickel complex, the first example of eta2-(Si-H)nickel complex by single-crystal X-ray analysis. Nickel 85-91 DNA polymerase iota Homo sapiens 161-165 15225021-1 2004 The reaction of (2-SiH3C6H4)2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2 afforded a new silylnickel complex, which, in the solid state, was determined to be a bis(silyl)eta2-(Si-H)nickel complex, the first example of eta2-(Si-H)nickel complex by single-crystal X-ray analysis. Nickel 85-91 DNA polymerase iota Homo sapiens 209-213 15099111-1 2004 Density functional theory indicates that oxidative addition of the C-F and C-H bonds in C6F6 and C6H6 at zerovalent nickel and platinum fragments, M(H2PCH2CH2PH2), proceeds via initial exothermic formation of an eta2-coordinated arene complex. Nickel 116-122 DNA polymerase iota Homo sapiens 212-216 33111387-1 2021 A nickel complex incorporating an N2O ligand with a rare eta2-N,N"-coordination mode was isolated and characterized by X-ray crystallography, as well as by IR and solid-state NMR augmented by 15N-labeling experiments. Nickel 2-8 DNA polymerase iota Homo sapiens 57-61 33111387-3 2021 Computational studies revealed that eta2-N2O binds to nickel slightly stronger than eta2-CO2 in this case, and comparably to or slightly stronger than eta2-CO2 to transition metals in general. Nickel 54-60 DNA polymerase iota Homo sapiens 36-40 21826370-4 2011 The crystal structure of 1 has been solved to show the coordination of nickel to the C-C bond of C(70) at the 6-6 ring junction of eta(2)-type to form Ni-C(C(70)) bonds of 1.929-1.941(2) A length, the shortest M-C bonds among those known for eta(2)-complexes of fullerenes C(60) and C(70). Nickel 71-77 DNA polymerase iota Homo sapiens 131-136 21826370-4 2011 The crystal structure of 1 has been solved to show the coordination of nickel to the C-C bond of C(70) at the 6-6 ring junction of eta(2)-type to form Ni-C(C(70)) bonds of 1.929-1.941(2) A length, the shortest M-C bonds among those known for eta(2)-complexes of fullerenes C(60) and C(70). Nickel 71-77 DNA polymerase iota Homo sapiens 242-247 16749844-0 2006 Molybdenum and tungsten eta2-alkyne-1-thio complexes acting as sulfur donors in homoleptic Werner type complexes with nickel(II) and palladium(II). Nickel 118-124 DNA polymerase iota Homo sapiens 24-28 29099520-1 2017 Reacting the low-valent nickel complex [(dtbpe)Ni]2(mu-eta2:eta2-C6H6) with oxaziridines was found to form mixtures of imine, amide and aldehyde products. Nickel 24-30 DNA polymerase iota Homo sapiens 55-59 29099520-1 2017 Reacting the low-valent nickel complex [(dtbpe)Ni]2(mu-eta2:eta2-C6H6) with oxaziridines was found to form mixtures of imine, amide and aldehyde products. Nickel 24-30 DNA polymerase iota Homo sapiens 60-64 29099520-5 2017 Preliminary mechanistic analysis is consistent with a bimetallic mechanism of fragmentation of the oxazanickelacyclobutane to form the nickel imido and eta2-aldehyde complexes. Nickel 104-110 DNA polymerase iota Homo sapiens 152-156 32558829-1 2020 An unprecedented nickel-catalyzed hydroarylative and hydroalkenylative cyclization of unsymmetrically substituted 1,6-dienes with organoboronic acid was developed by using MeOH as the hydrogen source and employing commercially available Ni(eta2-1,5-cyclooctadiene)2 as the catalyst. Nickel 17-23 DNA polymerase iota Homo sapiens 240-244 31860738-5 2020 The thermolysis of 3 leads to the tetrahedrane complex [(Cp"""Ni)2(micro,eta2:eta2-P)2] (5). Nickel 57-64 DNA polymerase iota Homo sapiens 73-77 31860738-5 2020 The thermolysis of 3 leads to the tetrahedrane complex [(Cp"""Ni)2(micro,eta2:eta2-P)2] (5). Nickel 57-64 DNA polymerase iota Homo sapiens 78-82 30113165-8 2018 In one of them, the imine adopts an uncommon eta1(N)eta2(C,N) bridging mode of the ligand to nickel, while the second one may involve reactivity on the ligand by the formation of a new C-C bond by oxidative coupling. Nickel 93-99 DNA polymerase iota Homo sapiens 52-56 29634236-7 2018 Two isolated nickel-CO2 adducts, (PPMeP)Ni(eta2-CO2-kappa C) (2) and {Na(12-C-4)2}{(PNP)Ni(eta1-CO2-kappa C)} (7), clearly demonstrate that the geometry of the nickel ion is crucial in the binding of CO2 and its level of activation. Nickel 13-19 DNA polymerase iota Homo sapiens 43-47 29152826-0 2018 Synthesis and Reactivity of Nickel-Stabilised mu2 :eta2 ,eta2 -P2 , As2 and PAs Units. Nickel 28-34 DNA polymerase iota Homo sapiens 51-55 29152826-0 2018 Synthesis and Reactivity of Nickel-Stabilised mu2 :eta2 ,eta2 -P2 , As2 and PAs Units. Nickel 28-34 DNA polymerase iota Homo sapiens 57-61