PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 18623277-3 1995 Furthermore, the rate of catalase-catalyzed production of tert-butanol from tert-butyl hydroperoxide increases more than 400-fold upon transition from aqueous buffer to ethanol as the reaction medium. tert-Butylhydroperoxide 76-100 catalase Bos taurus 25-33 18623277-4 1995 The mechanistic rationale for this striking effect is that in aqueous buffer the rate-limiting step of the enzymatic process involves the reduction of catalase"s compound I by tert-butyl hydroperoxide. tert-Butylhydroperoxide 176-200 catalase Bos taurus 151-159 18623277-6 1995 In solvents, such as acetonitrile or tetrahydrofuran, which themselves are not oxidizable by compound I, catalase catalyzes the oxidation of numerous primary and secondary alcohols with tert-butyl hydroperoxide to the corresponding aldehydes or ketones. tert-Butylhydroperoxide 186-210 catalase Bos taurus 105-113