PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 28598618-2 2017 This new methodology involves tandem (Ar)O-C(sp3) bond cleavage and C(sp2)/C(sp3)-SO2 formation toward divergent synthesis of sulfonyl- and phosphinyl-bifunctionalized 1,3-butadienes or allenes, depending on the substitution at the terminal carbon atoms of allenylphosphine oxides. 1,3-butadiene 168-182 Sp2 transcription factor Homo sapiens 68-73 18275171-1 2008 The bond length of a carbon-carbon sp2-sp2 sigma-bond without the perturbing effects of pi-interactions has been estimated by high level calculations on two prototypical systems: a 90 degrees -twisted form of butadiene and the tub conformer of cyclooctatetraene. 1,3-butadiene 209-218 Sp2 transcription factor Homo sapiens 35-38 18275171-1 2008 The bond length of a carbon-carbon sp2-sp2 sigma-bond without the perturbing effects of pi-interactions has been estimated by high level calculations on two prototypical systems: a 90 degrees -twisted form of butadiene and the tub conformer of cyclooctatetraene. 1,3-butadiene 209-218 Sp2 transcription factor Homo sapiens 39-42