PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 26189358-0 2015 Reaction Mechanism of the Symmetry-Forbidden [2+2] Addition of Ethylene and Acetylene to Amido-Substituted Digermynes and Distannynes Ph2N-EE-NPh2, (E = Ge, Sn): A Theoretical Study. ethylene 63-71 neurexophilin 2 Homo sapiens 142-146 26189358-1 2015 Quantum chemical calculations of reaction mechanisms for the formal [2+2] addition of ethylene and acetylene to the amido-substituted digermyne and distannyne Ph2N-EE-NPh2 (E = Ge, Sn) have been carried out by using density functional theory at the BP86/def2-TZVPP level. ethylene 86-94 neurexophilin 2 Homo sapiens 167-171 26189358-3 2015 The addition of ethylene to Ph2N-EE-NPh2 takes place through an initial [2+1] addition to one metal atom and consecutive rearrangement to four-membered cyclic species, which feature a weak E-E bond. ethylene 16-24 neurexophilin 2 Homo sapiens 36-40 26189358-5 2015 The overall reaction Ph2N-EE-NPh2+C2H4 (Ph2N)E-C2H4-E(NPh2) has very low activation barriers and is slightly exergonic for E = Ge but slightly endergonic for E = Sn. ethylene 34-38 neurexophilin 2 Homo sapiens 29-33 26189358-5 2015 The overall reaction Ph2N-EE-NPh2+C2H4 (Ph2N)E-C2H4-E(NPh2) has very low activation barriers and is slightly exergonic for E = Ge but slightly endergonic for E = Sn. ethylene 34-38 neurexophilin 2 Homo sapiens 54-58 26189358-7 2015 The energy partitioning analysis suggests that the HOMO(Ph2N-EE-NPh2) LUMO(C2H4) interaction has a similar strength as the HOMO(C2H4) LUMO(Ph2N-EE-NPh2) interaction. ethylene 75-79 neurexophilin 2 Homo sapiens 64-68 26189358-7 2015 The energy partitioning analysis suggests that the HOMO(Ph2N-EE-NPh2) LUMO(C2H4) interaction has a similar strength as the HOMO(C2H4) LUMO(Ph2N-EE-NPh2) interaction. ethylene 75-79 neurexophilin 2 Homo sapiens 147-151 26189358-7 2015 The energy partitioning analysis suggests that the HOMO(Ph2N-EE-NPh2) LUMO(C2H4) interaction has a similar strength as the HOMO(C2H4) LUMO(Ph2N-EE-NPh2) interaction. ethylene 128-132 neurexophilin 2 Homo sapiens 64-68 26189358-7 2015 The energy partitioning analysis suggests that the HOMO(Ph2N-EE-NPh2) LUMO(C2H4) interaction has a similar strength as the HOMO(C2H4) LUMO(Ph2N-EE-NPh2) interaction. ethylene 128-132 neurexophilin 2 Homo sapiens 147-151 34145658-1 2021 A dithiocarbamate chain transfer agent (CTA) based on Z-group substituted with a diphenyl amine (-NPh2 ) moiety is selected for the synthesis of statistical and diblock copolymers of ethylene and vinyl acetate via reversible addition-fragmentation chain transfer polymerization. ethylene 183-191 neurexophilin 2 Homo sapiens 98-102