PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 33164507-0 2020 Crystal Size Effect on the Spin-Crossover Behavior of {Fe(py)2[Pt(CN)4]} (py = Pyridine) Monitored by Raman Spectroscopy. pyridine 79-87 spindlin 1 Homo sapiens 27-31 30761702-2 2019 Upon addition of pyridine, both NiII centers became hexacoordinated by accepting two axial pyridines, which triggered a spin-state change of the NiII centers from diamagnetic (S=0) to paramagnetic (S=1). pyridine 17-25 spindlin 1 Homo sapiens 120-124 33780054-3 2021 The studied catalyst systems generate low-spin ( S = 1/2) oxoiron(V) intermediates or high-spin ( S = 3/2) oxoiron(V) intermediates, depending on the electron-donating ability of remote substituents at the pyridine rings. pyridine 208-216 spindlin 1 Homo sapiens 92-96 33475363-1 2021 In this work, we explore the interfacial properties of the C60-Py@MAPbI3 heterojunction of the PbI-terminated MAPbI3(001) surface and pyridine-functionalized C60-Py fullerene derivative through both collinear and noncollinear density functional theory calculations with and without spin-orbit coupling (SOC) effects. pyridine 134-142 spindlin 1 Homo sapiens 282-286 31002260-9 2019 The simultaneous application of two related pyridine derivatives is the efficient synthetic route for the multistep FeII SCO in the cyanido-bridged framework which is a promising step toward rational design of advanced spin transition molecular switches. pyridine 44-52 spindlin 1 Homo sapiens 219-223 17100424-2 2006 Nevertheless, recent studies have shown that approximate exchange-correlation energy density functionals can incorrectly predict the stability order of spin states in, for instance, iron-containing pyridine and imidazole systems. pyridine 198-206 spindlin 1 Homo sapiens 152-156 33164507-2 2020 Using variable-temperature Raman spectroscopy, we investigated changes in the temperature-driven spin-transition property of {Fe(py)2[Pt(CN)4]} (py = pyridine) induced by a size reduction from a bulk polycrystalline powder to an ultrathin film (crystallite size, 15 nm). pyridine 150-158 spindlin 1 Homo sapiens 97-101