PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
29579393-3	2018	We compare experimental redshifts and equilibrium constants, obtained by combining experiments and theory, for these complexes to the corresponding complexes with pyridine (sp2-hybridized N) and trimethylamine (sp3-hybridized N).	pyridine	163-171	Sp2 transcription factor	Homo sapiens	173-176	
28757942-2	2015	Subsequently, a unique C(sp2)-C(sp2) coupling of 2-phenylpyridine proceeded through a bimetallic yttrium intermediate, derived from an intramolecular shift of the yttrium center to an ortho-position of the pyridine ring in 3a, to yield a bimetallic yttrium complex (4a) bridged by two-electron reduced 6,6"-diphenyl-2,2"-bipyridyl.	pyridine	57-65	Sp2 transcription factor	Homo sapiens	23-28	
28757942-3	2015	Aryl substituents at the ortho-position of the pyridine ring were key in order to destabilize the mu,kappa2-(C,N)-pyridyldiyttrium intermediate prior to the C(sp2)-C(sp2) bond formation.	pyridine	47-55	Sp2 transcription factor	Homo sapiens	157-162	
28757942-3	2015	Aryl substituents at the ortho-position of the pyridine ring were key in order to destabilize the mu,kappa2-(C,N)-pyridyldiyttrium intermediate prior to the C(sp2)-C(sp2) bond formation.	pyridine	47-55	Sp2 transcription factor	Homo sapiens	164-169	
16933918-0	2006	Chemistry of HIV-1 virucidal Pt complexes having neglected bidentate sp2 N-donor carrier ligands with linked triazine and pyridine rings.	pyridine	122-130	Sp2 transcription factor	Homo sapiens	69-72	
23881771-0	2013	Pyridine-directed palladium-catalyzed phosphonation of C(sp2)-H bonds.	pyridine	0-8	Sp2 transcription factor	Homo sapiens	55-60	
34707193-2	2021	The sp2 carbon atoms adjacent to nitrogen in the pyridine ring provide pi-acceptor which forms a complex with filled d-orbital of native oxides on Cu and Ru metal film.	pyridine	49-57	Sp2 transcription factor	Homo sapiens	4-7	
30106306-4	2018	The reaction was found to begin with the C(sp2)-H oxidative addition of the pyridine ligand to give the Ir(III) hydride intermediate, from which the isomerization further takes place via the insertion/elimination pathway.	pyridine	76-84	Sp2 transcription factor	Homo sapiens	41-46	
33910228-0	2021	Phosphorus-mediated sp2-sp3 couplings for C-H fluoroalkylation of azines.	pyridine	66-72	Sp2 transcription factor	Homo sapiens	20-23	
31588947-1	2019	An efficient and convenient synthesis of diversely substituted naphtho[1",2":4,5]imidazo[1,2-a]-pyridine derivatives from the cascade reactions of 2-arylimidazo[1,2-a]pyridines with a-diazo carbonyl compounds via Rh(iii)-catalyzed regioselective C(sp2)-H alkylation followed by intramolecular annulation is presented.	pyridine	147-176	Sp2 transcription factor	Homo sapiens	246-251	
34015802-4	2021	This reactivity provides a mechanistically alternative tactic for sp2 carbon-boron bond assembly where the elementary steps of transition-metal mediated C-H activation and reductive elimination from azine-organometallic intermediates are replaced with a direct, Minisci9-style, radical addition.	pyridine	199-204	Sp2 transcription factor	Homo sapiens	66-69	
31589421-2	2019	A diverse array of unsubstituted N-heteroarenes including pyridine, pyrrole and pyrazine, traditionally challenging substrates for hydrogenation, were successfully hydrogenated using the organometallic precatalysts, (eta5-C5Me5)Rh(N-C)H (N-C = 2-phenylpyridinyl (ppy) or benzo[h]quinolinyl (bq)).	pyridine	58-66	Sp2 transcription factor	Homo sapiens	240-242	
31496256-2	2019	Highly selective C-C bond cleavage of gamma-substituted tert-propargyl alcohols occurred, together with pyridine-directed ortho C(sp2)-H bond activation, affording a series of 2-arylindoles with yields up to 90%.	pyridine	104-112	Sp2 transcription factor	Homo sapiens	128-133	
31408327-1	2019	The treatment of pyridine- and pyrazole-ligated NiII sigma-aryl complexes with Selectfluor results in C(sp2)-F bond formation under mild conditions.	pyridine	17-25	Sp2 transcription factor	Homo sapiens	102-107	
30562018-1	2019	A base-mediated protocol that allows for the site-selective sp2 C-H silylation of azines is described.	pyridine	82-88	Sp2 transcription factor	Homo sapiens	60-63