PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 14575452-3 2003 Trimer 1(3T) and tetramer 1(4T) were synthesized by Stille coupling of 2,5-dibromo-3,4-BCO-annelated thiophene 4 and of the 5,5"-dibromo derivative of bis(3,4-BCO-thiophen-2-yl) 10 with 2-stannylated 4,5-BCO-annelated thiophene 9 in 41% and 46% yield, respectively. Thiophenes 101-110 beta-carotene oxygenase 1 Homo sapiens 87-90 14575452-7 2003 Theoretical calculations for 1(2T) and 1(3T) at the B3LYP/6-31G(d) level indicated that the annelation with BCO units either at the 2,3- or 3,4-positions of thiophene rings raises both the KS HOMO and LUMO levels. Thiophenes 157-166 beta-carotene oxygenase 1 Homo sapiens 108-111