Title : Transition-metal-catalyzed regioselective aroyl- and trifluoro-acetylthiolation of alkynes using thioesters.

Pub. Date : 2009 Jun 7

PMID : 19462093






2 Functional Relationships(s)
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1 Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford beta-SR substituted enone derivatives; the choice of catalyst (Pd(dba)(2)-dppe) and the introduction of a CF(3) group into the thioesters are the key to achieving the transformation. Alkynes loss of heterozygosity, 19, chromosomal region 1 Homo sapiens
2 Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford beta-SR substituted enone derivatives; the choice of catalyst (Pd(dba)(2)-dppe) and the introduction of a CF(3) group into the thioesters are the key to achieving the transformation. beta-sr substituted enone loss of heterozygosity, 19, chromosomal region 1 Homo sapiens