Title : Alkyne gem-Hydrogenation: Formation of Pianostool Ruthenium Carbene Complexes and Analysis of Their Chemical Character.

Pub. Date : 2019 Jun 24

PMID : 31025788






1 Functional Relationships(s)
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1 Parahydrogen (p-H2 ) induced polarization (PHIP) NMR spectroscopy showed that [CpX Ru] complexes with greatly different electronic properties invariably engage propargyl alcohol derivatives into gem-hydrogenation with formation of pianostool ruthenium carbenes; in so doing, less electron rich CpX rings lower the barriers, stabilize the resulting complexes and hence provide opportunities for harnessing genuine carbene reactivity. Ruthenium polyhomeotic homolog 2 Homo sapiens