Title : Stereoselective synthesis of syn-configured alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids.

Pub. Date : 2009 Aug 21

PMID : 19630374






1 Functional Relationships(s)
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1 The resulting alkenylrhodium(I) intermediate undergoes beta-oxygen elimination to open the oxirane ring in a syn-selective fashion. Oxygen synemin Homo sapiens