| 1 |
34060818 | Enantioselective Ruthenium-BINAP-Catalyzed Carbonyl Reductive Coupling of Alkoxyallenes: Convergent Construction of syn-sec,tert-Diols via (Z)-σ-Allylmetal Intermediates. | 2021 Jun 16 |
1 |
| 2 |
34264662 | Synergistic Pd/Amine-Catalyzed Stereodivergent Hydroalkylation of 1,3-Dienes with Aldehydes: Reaction Development, Mechanism, and Stereochemical Origins. | 2021 Jul 28 |
1 |
| 3 |
34410708 | Nickel-Catalyzed Enantioselective Synthesis of Pre-Differentiated Homoallylic syn- or anti-1,2-Diols from Aldehydes and Dienol Ethers. | 2021 Sep 1 |
1 |
| 4 |
34436899 | Confinement-Controlled, Either syn- or anti-Selective Catalytic Asymmetric Mukaiyama Aldolizations of Propionaldehyde Enolsilanes. | 2021 Sep 15 |
1 |
| 5 |
31854991 | Calcium-Catalyzed Stereoselective Tandem [4+2] and [3+2] Annulation Reaction for the Synthesis of Dihydropyrrolo[1,2-a]quinolines. | 2020 Jan 3 |
1 |
| 6 |
33125249 | Enantioselective anti- and syn-(Borylmethyl)allylation of Aldehydes via Brønsted Acid Catalysis. | 2020 Nov 20 |
3 |
| 7 |
30996958 | (Z)-α-Boryl-crotylboron reagents via Z-selective alkene isomerization and application to stereoselective syntheses of (E)-δ-boryl-syn-homoallylic alcohols. | 2019 Mar 28 |
1 |
| 8 |
31067040 | Total Synthesis of Caprazamycin A: Practical and Scalable Synthesis of syn-β-Hydroxyamino Acids and Introduction of a Fatty Acid Side Chain to 1,4-Diazepanone. | 2019 May 29 |
1 |
| 9 |
31720519 | NMR and Computational Studies on the Reactions of Enamines with Nitroalkenes That May Pass through Cyclobutanes. | 2019 Nov 5 |
1 |
| 10 |
29507642 | Syn-selective silicon Mukaiyama-type aldol reactions of (pentafluoro-λ6-sulfanyl)acetic acid esters with aldehydes. | 2018 |
1 |
| 11 |
29617147 | Prolinate Salt as a Catalyst in the syn-Selective, Asymmetric Mannich Reaction of Alkynyl Imine. | 2018 Apr 20 |
1 |
| 12 |
30256121 | Enantioselective syn- and anti-Alkoxyallylation of Aldehydes via Brønsted Acid Catalysis. | 2018 Oct 5 |
1 |
| 13 |
30489077 | Nickel Catalyzed syn-Selective Aryl Nickelation and Cyclization of Aldehyde/Enone-Tethered Terminal Alkynes with Arylboronic Acids. | 2018 Dec 21 |
1 |
| 14 |
28406519 | syn-Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: some synthetic applications. | 2017 May 3 |
2 |
| 15 |
28471668 | Enantio- and Diastereoselective Synthesis of 1,5-syn-(Z)-Amino Alcohols via Imine Double Allylboration: Synthesis of trans-1,2,3,6-Tetrahydropyridines and Total Synthesis of Andrachcine. | 2017 May 19 |
1 |
| 16 |
28731121 | Unified total synthesis of (+)-chinensiolide B and (+)-8-epigrosheimin. | 2017 Aug 2 |
2 |
| 17 |
28960976 | Stereochemical Characterization of Polyketide Stereotriads Synthesized via Hydrogen-Mediated Asymmetric syn-Crotylation. | 2017 Oct 20 |
3 |
| 18 |
26771707 | Nickel-Catalyzed Double Bond Transposition of Alkenyl Boronates for in Situ syn-Selective Allylboration Reactions. | 2016 Feb 5 |
1 |
| 19 |
26991332 | Development of a syn-Selective Mannich Reaction of Aldehydes with Propargylic Imines by Dual Catalysis: Asymmetric Synthesis of Functionalized Propargylic Amines. | 2016 May 17 |
2 |
| 20 |
27400735 | Development of a Simple Adjustable Zinc Acid/Base Hybrid Catalyst for C-C and C-O Bond-Forming and C-C Bond-Cleavage Reactions. | 2016 Sep 6 |
1 |
| 21 |
27482931 | Stereoselective Chirality Extension of syn,anti- and syn,syn-Oxazine and Stereochemical Analysis of Chiral 1,3-Oxazines: Stereoselective Total Syntheses of (+)-1-Deoxygalactonojirimycin and (-)-1-Deoxygulonojirimycin. | 2016 Sep 2 |
3 |
| 22 |
26488447 | Organocatalyzed Multicomponent Synthesis of Isoxazolidin-5-ones. | 2015 Nov 6 |
1 |
| 23 |
24499418 | [1,5]-Anion relay via intramolecular proton transfer to generate 3,3-bis(silyl) allyloxy lithium: a useful scaffold for syn-addition to aldehydes and ketones. | 2014 Feb 21 |
2 |
| 24 |
24735355 | Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry. | 2014 Apr 30 |
2 |
| 25 |
25068433 | The stereoselective synthesis of α-amino aldols starting from terminal alkynes. | 2014 Sep 18 |
1 |
| 26 |
25144919 | Crystal structure, matrix-isolation FTIR, and UV-induced conformational isomerization of 3-quinolinecarboxaldehyde. | 2014 Sep 25 |
1 |
| 27 |
25280088 | Investigation of diastereoselective acyclic α-alkoxydithioacetal substitutions involving thiacarbenium intermediates. | 2014 Nov 7 |
1 |
| 28 |
23259754 | Total synthesis of sedum alkaloids via catalyst controlled aza-Cope rearrangement and hydroformylation with formaldehyde. | 2013 Jan 18 |
1 |
| 29 |
23442005 | Density functional study of organocatalytic cross-aldol reactions between two aliphatic aldehydes: insight into their functional differentiation and origins of chemo- and stereoselectivities. | 2013 Apr 4 |
1 |
| 30 |
23576096 | Stereoselective titanium-mediated aldol reactions of a chiral isopropyl ketone. | 2013 May 18 |
1 |
| 31 |
23589825 | Pd-catalyzed diastereoselective allylation of aldehydes with 3-bromomethyl-5H-furan-2-one: stereoselective synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones with a syn configuration. | 2013 May 21 |
1 |
| 32 |
23606588 | Synthesis of 8-desmethoxy psymberin: a putative biosynthetic intermediate towards the marine polyketide psymberin. | 2013 Jun 17 |
1 |
| 33 |
24281803 | syn- and enantioselective Henry reactions of aliphatic aldehydes and application to the synthesis of safingol. | 2013 Dec 2 |
1 |
| 34 |
22258739 | Stereocontrolled asymmetric synthesis of syn-E-1,4-diol-2-enes using allyl boronates and its application in the total synthesis of solandelactone F. | 2012 Mar 7 |
1 |
| 35 |
22278901 | Asymmetric Michael reaction of aldehydes with β-nitroalkenes catalyzed by pyrrolidine-camphor derived organocatalysts bearing hydrogen-bond donors. | 2012 Apr |
1 |
| 36 |
22431296 | Asymmetric nucleophilic monofluorobenzylation of carbonyl compounds: synthesis of enantiopure vic-fluorohydrins and α-fluorobenzylketones. | 2012 Apr 23 |
1 |
| 37 |
22646839 | Diastereo- and enantioselective synthesis of (E)-2-Methyl-1,2-syn- and (E)-2-Methyl-1,2-anti-3-pentenediols via allenylboronate kinetic resolution with ((d)Ipc)2BH and aldehyde allylboration. | 2012 Jun 15 |
2 |
| 38 |
22684237 | Molecular recognition of ketomalonates by asymmetric aldol reaction of aldehydes with secondary-amine organocatalysts. | 2012 Jul 18 |
1 |
| 39 |
23154487 | Total syntheses of pamamycin 607 and methyl nonactate: stereoselective cyclisation of homoallylic alcohols that had been prepared with remote stereocontrol using allylstannanes. | 2012 Dec 28 |
1 |
| 40 |
20963247 | Direct carbon-carbon bond formation via soft enolization: aldol addition of α-halogenated thioesters. | 2011 Jan 7 |
1 |
| 41 |
21174471 | A highly diastereo- and enantioselective copper(I)-catalyzed Henry reaction using a bis(sulfonamide)-diamine ligand. | 2011 Jan 21 |
2 |
| 42 |
21359299 | Asymmetric syn-selective direct aldol reaction of protected hydroxyacetone catalyzed by primary amino acid derived bifunctional organocatalyst in the presence of water. | 2011 Apr 21 |
3 |
| 43 |
21375316 | Enantio- and diastereoselective synthesis of (E)-1,5-syn-diols: application to the synthesis of the C(23)-C(40) fragment of tetrafibricin. | 2011 Apr 1 |
1 |
| 44 |
21410173 | Enantioselective syntheses of syn- and anti-β-hydroxyallylsilanes via allene hydroboration-aldehyde allylboration reactions. | 2011 Apr 15 |
2 |
| 45 |
21556397 | Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts. | 2011 Jun 21 |
1 |
| 46 |
21657276 | Diastereodivergent behavior of alkyl versus cyano allenylcuprates toward aldehydes: a key role for lithium. | 2011 Jul 20 |
1 |
| 47 |
21857752 | Development of a Double Allylboration Reagent Targeting 1,5-syn-(E)-Diols: Application to the Synthesis of the C(23)-C(40) Fragment of Tetrafibricin. | 2011 Sep 2 |
1 |
| 48 |
21892467 | syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide. | 2011 Oct 14 |
2 |
| 49 |
21958056 | N-Prolinylanthranilamide pseudopeptides as bifunctional organocatalysts for asymmetric aldol reactions. | 2011 Oct 21 |
1 |
| 50 |
20000733 | TiCl4-promoted Baylis-Hillman reaction: mechanistic rationale toward product distribution and stereoselectivity. | 2010 Jan 15 |
1 |