PMID-sentid Pub_year Sent_text compound_name comp_offset prot_official_name organism prot_offset 21542347-3 2011 It has been shown that the prooxidant action of Ca2+ is related to an abrupt increase (approximately by three orders of magnitude) in the rate constant of comproportionation (reaction of chain branching and formation of o-semiquinonates) and a marked decrease (by two orders of magnitude, from 1.4 10(7) to 0.6 10(5) M(-1)s(-1)) in the rate constant of disproportionation of o-semiquinones. o-semiquinones 375-389 carbonic anhydrase 2 Homo sapiens 48-51 23143010-11 2012 Only the application of o-semiquinones as spin labels and using the EPR technique made possible to observe and interpret their structure. o-semiquinones 24-38 spindlin 1 Homo sapiens 42-46 9659366-0 1998 Metabolic activation of dopamine o-quinones to o-semiquinones by NADPH cytochrome P450 reductase may play an important role in oxidative stress and apoptotic effects. o-semiquinones 47-61 cytochrome p450 oxidoreductase Homo sapiens 65-96