PMID-sentid Pub_year Sent_text compound_name comp_offset prot_official_name organism prot_offset 24533895-1 2014 The salt Fe(OTf)3 has been shown to function as an effective catalyst in three different reactions, epoxide oxidative ring-opening to an alpha-hydroxy ketone, urea alpha-diketone condensation to form glycolurils, and glycoluril diether synthesis by formaldehyde condensation. alpha-hydroxy ketone 137-157 POU class 5 homeobox 1 Homo sapiens 12-17 15709774-4 2005 The similar yields of [1(R)-(2)H]-DHAP and [2(R)-(2)H]-GAP from partitioning of the enzyme-bound enediol(ate) intermediate between hydron transfer to C-1 and C-2 is consistent with earlier results, which showed that there are similar barriers for conversion of this intermediate to the alpha-hydroxy ketone and aldehyde products (Knowles, J. R., and Albery, W. J. alpha-hydroxy ketone 286-306 complement C2 Oryctolagus cuniculus 150-161 26079654-4 2015 The hydroxyl at C-23 was more reactive than the 22-OH in the oxidation with bromine in the presence of bis(tributyltin) oxide and in the benzylation reaction that resulted in the predominant formation of the corresponding alpha-hydroxy ketone derivatives with the ratio ranging from 4:1 to 1.5:1. alpha-hydroxy ketone 222-242 nucleolin Homo sapiens 16-20