PMID-sentid	Pub_year	Sent_text	compound_name	comp_offset	prot_official_name	organism	prot_offset
18177039-4	2008	The greater propensity of methyl(trifluoromethyl)dioxirane TFDO (1b) to act as an electrophilic oxidant with respect to dimethyldioxirane DDO (1a) parallels the cathode reduction potentials for the two dioxiranes, as measured by cyclic voltammetry.	dimethyldioxirane	120-137	D-aspartate oxidase	Homo sapiens	138-141
24548247-2	2014	We report a mild, one-pot conversion of glycals into beta-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can be generated in situ from secondary amines and CS2.	dimethyldioxirane	76-80	chorionic somatomammotropin hormone 2	Homo sapiens	191-194
11674543-5	1999	High syn-diastereoselectivity is achieved in the epoxidation of the primary allylic salt 3aH(+)() while the quaternary allylic ammonium salt 5a(+)() gives equimolecular (m-CPBA) or predominantly anti(DMDO) mixtures of diastereomers.	dimethyldioxirane	200-204	synemin	Homo sapiens	5-8
12633071-1	2003	[reaction: see text] Dimethyldioxirane oxidizes a 2,3-dihydo-1H-pyrrolo[1,2-a]indole unsubstituted at the C-9 position stereoselectively to form a hydroxy ketone with all the basic elements of the mitomycin ring system.	dimethyldioxirane	21-38	complement C9	Homo sapiens	106-109
12633071-2	2003	On the other hand, a 2,3-dihydo-1H-pyrrolo[1,2-a]indole derivative substituted with an alkyl group at C-9 undergoes an oxidative ring expansion in the presence of dimethyldioxirane to give an FR900482 analogue.	dimethyldioxirane	163-180	complement C9	Homo sapiens	102-105
12784869-2	2003	DMDO oxidation of stereoisomeric methyl 3alpha,6-diacetoxy-5beta-cholanoates caused the direct, unexpected 14alpha- and 17alpha-hydroxylations, in analogy with that of the 5alpha-H analogs, regardless of the differences in stereochemical configuration of the A/B-ring junction and of the acetoxyl groups at C-3 and C-6.	dimethyldioxirane	0-4	complement C6	Homo sapiens	315-318
15624982-1	2005	Treatment of highly potent and densely functionalized bryostatin analogue 1 with dimethyldioxirane afforded the C-9 hydroxylated hemiketal 2 via oxyfunctionalization of the C9-CH bond, one of 12 CH bonds geminal to an oxygen substituent in 1.	dimethyldioxirane	81-98	complement C9	Homo sapiens	112-115
12372858-4	2002	The key reaction involved one-step remote oxyfunctionalization of unactivated methine carbons at C-17 of CDCA and at C-14 of UDCA as their methyl ester-peracetate derivatives with dimethyldioxirane (DMDO).	dimethyldioxirane	199-203	cytokine like 1	Homo sapiens	97-101